Ali Badrut Tamam Ibnu, Kusumawati Yuly, Jaafar Juhana, Sulistiono Dety Oktavia, Widiastuti Nurul
Department of Chemistry, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember Jl. Arif Rahman Hakim, Kampus ITS Keputih-Sukolilo Surabaya 60111 Indonesia
Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia 81310 Skudai Johor Bahru Malaysia.
RSC Adv. 2023 Mar 17;13(13):8985-8995. doi: 10.1039/d3ra00827d. eCollection 2023 Mar 14.
River water has become contaminated with numerous hazardous compounds due to the rapid rise in population and industry expansion. Due to unchecked population growth and the improper disposal of electroplating industrial waste, issues with river water filtration and the elimination of chromium contamination have developed. Various technologies have been developed to overcome these problems. One of the technologies that have been proposed until now is membrane technology. On the other hand, the waste from plastic bottles, which grows yearly and now weighs 381.73 million tons, can create thin films or layers. Therefore, there is a lot of potential in employing plastic bottle trash as a low-cost, sustainable, and eco-friendly membrane material. In this study, the immersion-precipitation phase inversion method was used in the membrane preparation process from plastic bottle waste by modifying fillers (zeolite-NaY) and additives (LiCl and PEG-400) to improve membrane performance. The effect of filler and additive modification on the fabricated membrane was studied for its performance in water purification and chromium ion contaminant removal. The results demonstrated that the modified LiCl membrane performed optimally for water purification and the removal of chromium ions, along with a reduction in turbidity to 1.42 NTU (from 400 NTU) and a 54.75% removal of chromium.
由于人口的快速增长和工业的扩张,河水已被大量有害化合物污染。由于人口增长失控以及电镀工业废物的不当处置,河水过滤和铬污染消除问题日益凸显。人们已开发出各种技术来克服这些问题。到目前为止,所提出的技术之一是膜技术。另一方面,塑料瓶产生的废物逐年增加,目前重达3.8173亿吨,可制成薄膜或层。因此,将塑料瓶垃圾用作低成本、可持续且环保的膜材料具有很大潜力。在本研究中,采用浸没沉淀相转化法,通过改性填料(沸石-NaY)和添加剂(LiCl和PEG-400)从塑料瓶废料制备膜,以提高膜性能。研究了填料和添加剂改性对制成的膜在水净化和去除铬离子污染物方面性能的影响。结果表明,改性LiCl膜在水净化和铬离子去除方面表现最佳,浊度从400 NTU降至1.42 NTU,铬去除率达54.75%。