Department of Chemistry, Northwestern University, 2145 Sheridan Rd, Evanston, IL 60208, USA.
Nat Prod Rep. 2023 Apr 26;40(4):890-921. doi: 10.1039/d2np00064d.
Covering: 1997 up to 2022Volatile biogenic terpenes involved in the formation of secondary organic aerosol (SOA) particles participate in rich atmospheric chemistry that impacts numerous aspects of the earth's complex climate system. Despite the importance of these species, understanding their fate in the atmosphere and determining their atmospherically-relevant properties has been limited by the availability of authentic standards and probe molecules. Advances in synthetic organic chemistry directly aimed at answering these questions have, however, led to exciting discoveries at the interface of chemistry and atmospheric science. Herein we provide a review of the literature regarding the synthesis of commercially unavailable authentic standards used to analyze the composition, properties, and mechanisms of SOA particles in the atmosphere.
1997 年至今
参与二次有机气溶胶（SOA）颗粒形成的挥发性生物源萜类化合物参与了丰富的大气化学过程，这些过程会影响地球复杂气候系统的众多方面。尽管这些物质非常重要，但由于缺乏真实的标准品和探针分子，对其在大气中的命运及其具有大气相关性的性质的了解受到了限制。然而，直接针对回答这些问题的合成有机化学方面的进展，在化学和大气科学的界面上带来了令人兴奋的发现。在此，我们综述了有关合成商业上无法获得的真实标准品的文献，这些标准品用于分析大气中 SOA 颗粒的组成、性质和机制。
