Beijing Advanced Innovation Center for Materials Genome Engineering, Beijing Key Laboratory of Function Materials for Molecule & Structure Construction, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China.
Institute of Advanced Materials, Beijing Normal University, Beijing 100875, China.
Chem Rev. 2023 Jun 14;123(11):6953-7024. doi: 10.1021/acs.chemrev.2c00572. Epub 2023 Mar 22.
Functional phase change materials (PCMs) capable of reversibly storing and releasing tremendous thermal energy during the isothermal phase change process have recently received tremendous attention in interdisciplinary applications. The smart integration of PCMs with functional supporting materials enables multiple cutting-edge interdisciplinary applications, including optical, electrical, magnetic, acoustic, medical, mechanical, and catalytic disciplines etc. Herein, we systematically discuss thermal storage mechanism, thermal transfer mechanism, and energy conversion mechanism, and summarize the state-of-the-art advances in interdisciplinary applications of PCMs. In particular, the applications of PCMs in acoustic, mechanical, and catalytic disciplines are still in their infancy. Simultaneously, in-depth insights into the correlations between microscopic structures and thermophysical properties of composite PCMs are revealed. Finally, current challenges and future prospects are also highlighted according to the up-to-date interdisciplinary applications of PCMs. This review aims to arouse broad research interest in the interdisciplinary community and provide constructive references for exploring next generation advanced multifunctional PCMs for interdisciplinary applications, thereby facilitating their major breakthroughs in both fundamental researches and commercial applications.
功能相变材料(PCM)在等温相变过程中能够可逆地存储和释放大量热能,最近在跨学科应用中受到了极大关注。PCM 与功能支撑材料的智能集成使多个前沿跨学科应用成为可能,包括光学、电气、磁性、声学、医疗、机械和催化等学科。在此,我们系统地讨论了 PCM 的热存储机制、热传递机制和能量转换机制,并总结了 PCM 在跨学科应用中的最新进展。特别是 PCM 在声学、机械和催化学科中的应用仍处于起步阶段。同时,深入揭示了复合 PCM 的微观结构与热物理性能之间的相关性。最后,根据 PCM 的最新跨学科应用,突出了当前的挑战和未来的前景。本综述旨在引起跨学科领域的广泛研究兴趣,并为探索下一代用于跨学科应用的先进多功能 PCM 提供建设性参考,从而促进它们在基础研究和商业应用方面的重大突破。