Theoretical performance studies on environment friendly refrigerants used in refrigeration units.

European Union regulations stipulate that household refrigeration systems must operate with fluid refrigerants that possess low global warming potential (GWPs). In this work, theoretical performance of six binary and one ternary mixture (which consists of R13I1, R290, R161, R32, R1234yf, and R1234ze(E)) was investigated. The performance parameters such as coefficient of performance (COP), refrigeration effect (RE), volumetric cooling capacity (VCC), discharge temperature, pressure ratio, and specific power consumption of all considered refrigerant mixtures is studied with respect to the evaporator temperature range of -18 to 18C and the condenser temperature range of 40 to 55C. The properties corresponding to different operating conditions for the refrigerants considered in this study are estimated using REFPROP 10. The findings demonstrated that, when compared to R134a, all the investigated refrigerants exhibited very low specific power consumption (apart from M9, M10, and M14-M16), and high volumetric cooling capacity (VCC) (apart from M11 and M13) under the operating conditions of evaporator temperature -18C and condenser temperature 40C. M1-M3 and M11-M13 gave similar and within 10% deviation in coefficient of performance, while M3 and M11-M13 refrigerant mixtures offer significantly low discharge temperatures when compared to R134a. Refrigerant mixtures M2 and M11 consistently exhibited a better performance in comparison to R134a in the aspect of majority of the performance parameters considered in this study. Finally, it is understood that M2 and M11 are two possible alternative refrigerants to conventional refrigerants used in small refrigeration units (R134a and R22). Further, it is also identified that these mixtures are non-flammable, possess zero ODP and low GWP values.