Anbarani Mohaddeseh Zahmatkesh, Ramavandi Bahman, Bonyadi Ziaeddin
Department of Environmental Health Engineering, School of Health, Mashhad University of Medical Sciences, Mashhad, Iran.
Department of Environmental Health Engineering, Faculty of Health, Bushehr University of Medical Sciences, Bushehr, Iran.
Heliyon. 2023 Mar 6;9(3):e14356. doi: 10.1016/j.heliyon.2023.e14356. eCollection 2023 Mar.
Tetracycline (TTC) is an antibiotic commonly prescribed to treat bacterial infections in animals and humans because of its low toxicity and antibacterial activity. This study focuses on the removal of TTC from an aqueous media using an activated carbon of modified with FeO magnetic composite (ACCV/FeO mc). The isothermal and kinetic models were studied to understand the adsorption mechanism. The Box-Behnken model was used for experimental design, and the main research parameters were ACCV/FeO mc mass (0.2-0.8 g/L), reaction time (10-60 min), TTC concentration (5-30 mg/L), and pH (3-11). The highest TTC removal rate of 90.47% was obtained at a pH of 7, a time of 60 min, an ACCV/FeO mc mass of 0.5 g/L, and an antibiotic concentration of 5 mg/L. TTC removal was fitted with the pseudo-second-order and the Langmuir model. The Langmuir adsorption capacity of TTC was computed to be 26.18 mg/g. The results show that the ACCV/FeO mc adsorbent significantly removes TTC from the aqueous solution.
四环素(TTC)是一种抗生素,因其低毒性和抗菌活性,常用于治疗动物和人类的细菌感染。本研究聚焦于使用FeO磁性复合材料改性的活性炭(ACCV/FeO mc)从水介质中去除TTC。对等温吸附模型和动力学模型进行了研究,以了解吸附机理。采用Box-Behnken模型进行实验设计,主要研究参数为ACCV/FeO mc质量(0.2 - 0.8 g/L)、反应时间(10 - 60分钟)、TTC浓度(5 - 30 mg/L)和pH值(3 - 11)。在pH值为7、时间为60分钟、ACCV/FeO mc质量为0.5 g/L以及抗生素浓度为5 mg/L的条件下,获得了90.47%的最高TTC去除率。TTC的去除符合准二级动力学模型和朗缪尔模型。计算得出TTC的朗缪尔吸附容量为26.18 mg/g。结果表明,ACCV/FeO mc吸附剂能显著从水溶液中去除TTC。