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一种新型阳离子染料的合成,用于赋予丙烯酸织物驱蚊和紫外线防护功能。

Synthesis of a Novel Cationic Dye to Impart Mosquito-Repellent and UV Protection to an Acrylic Fabric.

作者信息

Singh Ankit, Sheikh Javed

机构信息

Department of Textile and Fibre Engineering, Indian Institute of Technology Delhi, New Delhi 110016, India.

出版信息

ACS Omega. 2023 Mar 13;8(11):10214-10224. doi: 10.1021/acsomega.2c07693. eCollection 2023 Mar 21.

Abstract

The growing demand for innovative routes to develop functional textiles initiated the necessity of new efficient functional molecules. Dyes can provide durable functional protection to textiles due to their ability to generate strong dye-fiber interaction. New dyes to improve a dyed substrate's quality and aesthetic appearance are in huge demand. This research aims to prepare a mosquito-repellent and UV-protective acrylic fabric using a novel cationic (basic) dye. The cationic dye was synthesized and thoroughly characterized with the help of FTIR, H NMR, C NMR, and CHN analysis. The dye was further used for the dyeing of the acrylic fabric by using an infrared dyeing machine. To analyze the suitability of dyed fabrics for daily use, washing, rubbing, and light fastness of dyed fabrics were determined. The amount of dye (%) taken up by the acrylic fabric (exhaustion %) was determined, and more than 72% of exhaustion was obtained. The fixation (%) of the dye on acrylic fabrics was also quantified, and more than 80% fixation was obtained. The coloration properties of the dyed fabrics (*, *, *, and /) were examined. The dyed fabrics showed a / of more than 3. The mosquito-repellent action provided by the dyed fabrics was also analyzed, and 100% repellency was obtained. The dyed fabrics provided an excellent UV-protective property. The multifunctional properties of dyed fabrics were retained significantly even after laundering treatments. The dyed fabrics were characterized using X-ray diffraction and thermogravimetric analysis. A reduction in crystalline peak intensity after dyeing was obtained. The dyed and undyed fabrics were also tested for their tensile strength.

摘要

对开发功能性纺织品的创新途径的需求不断增长,引发了对新型高效功能分子的需求。由于染料能够产生强烈的染料 - 纤维相互作用,因此可以为纺织品提供持久的功能保护。人们对能够提高染色基材质量和美学外观的新型染料有巨大需求。本研究旨在使用一种新型阳离子(碱性)染料制备具有驱蚊和紫外线防护功能的腈纶织物。合成了阳离子染料,并借助傅里叶变换红外光谱(FTIR)、氢核磁共振(¹H NMR)、碳核磁共振(¹³C NMR)和元素分析(CHN)对其进行了全面表征。该染料进一步通过红外染色机用于腈纶织物的染色。为了分析染色织物在日常使用中的适用性,测定了染色织物的耐洗色牢度、耐摩擦色牢度和耐光色牢度。测定了腈纶织物对染料的上染率(%),上染率超过72%。还对染料在腈纶织物上的固色率(%)进行了量化,固色率超过80%。研究了染色织物的颜色特性(、*和/)。染色织物的/值大于3。还分析了染色织物提供的驱蚊作用,驱蚊率达到100%。染色织物具有优异的紫外线防护性能。即使经过洗涤处理,染色织物的多功能性能仍能显著保留。使用X射线衍射和热重分析对染色织物进行了表征。染色后结晶峰强度降低。还对染色和未染色织物的拉伸强度进行了测试。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/def9/10034786/fb6babc397b3/ao2c07693_0002.jpg

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