Study on the Preparation of Montmorillonite-Type Multiple Network Composite Gel for Coal Spontaneous Combustion and Its Firefighting Mechanism.

This paper proposes a new montmorillonite-type multiple network composite gel for the prevention of coal spontaneous combustion. The first network is formed by the cross-linking of polyvinyl alcohol (PVA) and boric acid under alkaline conditions. The second network is formed as a result of intermolecular hydrogen-bonding interactions between polyacrylamide (PAM) and polyvinyl alcohol. Montmorillonite (MMT) is designed as the backbone material in the preparation of composite gels. The optimal ratios of the reactants of the composite gel were determined through orthogonal experiments. The experimental results showed that PVA had the greatest influence on the gelation time, whereas the PAM concentration had the strongest influence on the gel permeability. The optimal blending ratio was 4% MMT + 2.5% PVA + 1.5% PAM. The chemical performances of the composite colloids, such as inhibition rate, reactive functional groups, and kinetics, were investigated. Results showed that multiple network composite gels could effectively inhibit the coal spontaneous combustion reaction. Based on the principle of coal spontaneous combustion and the cross-linking network structure of the composite gel, the flame-retardant and fire-extinguishing mechanisms were also explored in terms of both physical and chemical inhibition pathways.