Li Jing, Cui Chuanzhi, Wu Zhongwei, Yi Jiqing, Zong Ran, Fu Yihui, Han Xingyuan
School of Petroleum Engineering, China University of Petroleum (East China), Qingdao, Shandong 266580, China.
School of Petroleum Engineering, Yangtze University, Wuhan, Hubei 430199, China.
ACS Omega. 2023 Mar 9;8(11):10062-10076. doi: 10.1021/acsomega.2c07393. eCollection 2023 Mar 21.
CO miscible flooding in low permeability reservoirs is conducive to significantly improving oil recovery. At present, the microscopic displacement simulation of CO miscible flooding is mainly reflected in the simulation of the seepage process, but the pressure control of the seepage process is lacking, and the simulation of the characterization of CO concentration diffusion is less studied. In view of the above problems, a numerical model of CO miscible flooding is established, and the microscopic seepage characteristics of interphase mass transfer in CO miscible flooding are analyzed by multiphysics field coupling simulations at the two-dimensional pore scale. The injection velocity, contact angle, diffusion coefficient, and initial injection concentration are selected to analyze their effects on the microscopic seepage characteristics of CO miscible flooding and the concentration distribution in the process of CO diffusion. The research shows that after injection into the model, CO preferentially diffuses into the large pore space and forms a miscible area with crude oil through interphase mass transfer, and the miscible area expands continuously and is pushed to the outlet by the high CO concentration area. The increase in injection velocity will accelerate the seepage process of CO miscible displacement, which will increase the sweep area at the same time. The increase in contact angle increases the seepage resistance of CO and weakens the interphase mass transfer with crude oil, resulting in a gradual decrease in the final recovery efficiency. When the diffusion coefficient increases, the CO concentration in the small pores and the parts that are difficult to reach at the model edge will gradually increase. The larger the initial injection concentration is, the larger the CO concentration in the large pore and miscible areas in the sweep region at the same time. This study has guiding significance for the field to further understand the microscopic seepage characteristics of CO miscible flooding under the effect of interphase mass transfer.
二氧化碳混相驱油在低渗透油藏中有利于显著提高采收率。目前,二氧化碳混相驱微观驱替模拟主要体现在渗流过程模拟,但缺乏对渗流过程的压力控制,对二氧化碳浓度扩散特征模拟的研究较少。针对上述问题,建立了二氧化碳混相驱数值模型,通过二维孔隙尺度的多物理场耦合模拟分析了二氧化碳混相驱相间传质微观渗流特征。选取注入速度、接触角、扩散系数和初始注入浓度,分析其对二氧化碳混相驱微观渗流特征及二氧化碳扩散过程中浓度分布的影响。研究表明,注入模型后,二氧化碳优先扩散至大孔隙空间,通过相间传质与原油形成混相区域,混相区域不断扩展并被高二氧化碳浓度区域推向出口。注入速度的增加会加速二氧化碳混相驱替的渗流过程,同时增大波及面积。接触角的增大增加了二氧化碳的渗流阻力,削弱了与原油的相间传质,导致最终采收率逐渐降低。当扩散系数增大时,模型边缘小孔隙及难以到达部位处的二氧化碳浓度将逐渐升高。初始注入浓度越大,同一时刻波及区域内大孔隙及混相区域的二氧化碳浓度越大。该研究对于现场进一步认识相间传质作用下二氧化碳混相驱微观渗流特征具有指导意义。