School of Metallurgy and Environment, Central South University, Changsha 410083, China.
Linxiang Station of Yueyang Ecology and Environment Monitoring Center, Linxiang 414300, China.
Int J Environ Res Public Health. 2023 Mar 14;20(6):5097. doi: 10.3390/ijerph20065097.
It is highly uncertain as to the potential risk of toxic metal(loid)s in abandoned mine soil. In this study, random forest was used to predict the risk of cadmium pollution in the soils of an abandoned lead/zinc mine. The results showed that the random forest model is stable and precise for the pollution risk prediction of toxic metal(loid)s. The mean of Cd, Cu, Tl, Zn, and Pb was 6.02, 1.30, 1.18, 2.03, and 2.08 times higher than the soil background values of China, respectively, and their coefficients of variation were above 30%. As a case study, cadmium in the mine soil had "slope" hazard characteristics while the ore sorting area was the major source area of cadmium. The theoretical values of the random forest model are similar to the practical values for the ore sorting area, metallogenic belt, riparian zone, smelting area, hazardous waste landfill, and mining area. The potential risk of soil Cd in the ore sorting area, metallogenic belt, and riparian zone are extremely high. The tendency of pollution risk migrates significantly both from the ore sorting area to the smelting area and the mining area, and to the hazardous waste landfill. The correlation of soil pollution risk is significant between the mining area, the smelting area, and the riparian zone. The results suggested that the random forest model can effectively evaluate and predict the potential risk of the spatial heterogeneity of toxic metal(loid)s in abandoned mine soils.
废弃矿山土壤中有毒金属(类)的潜在风险尚不确定。本研究采用随机森林方法预测了某废弃铅锌矿土壤中镉污染的风险。结果表明,随机森林模型对于有毒金属(类)污染风险的预测具有较好的稳定性和精度。土壤中 Cd、Cu、Tl、Zn 和 Pb 的均值分别是中国土壤背景值的 6.02、1.30、1.18、2.03 和 2.08 倍,其变异系数均大于 30%。作为案例研究,矿山土壤中的镉具有“陡坡”危害特征,而矿石选别区是镉的主要源区。随机森林模型的理论值与矿石选别区、成矿带、滨河区、冶炼区、危险废物填埋场和采矿区的实际值相似。矿石选别区、成矿带和滨河区土壤 Cd 的潜在风险极高。污染风险的迁移趋势从矿石选别区明显向冶炼区和采矿区以及危险废物填埋场迁移。矿区、冶炼区和滨河区土壤污染风险具有显著相关性。结果表明,随机森林模型可有效评价和预测废弃矿山土壤中有毒金属(类)空间异质性的潜在风险。