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新型退火与喷砂复合处理对TA1焊接钛板微观结构及性能的影响

The Effect of Novel Complex Treatment of Annealing and Sandblasting on the Microstructure and Performance of Welded TA1 Titanium Plate.

作者信息

Xu Yanbin, Wang Dayue, Li Mingyen, Hu Jing, An Xulong, Wei Wei

机构信息

Jiangsu Key Laboratory of Materials Surface Science and Technology, Huaide College, Changzhou University, Changzhou 213164, China.

National Experimental Demonstration Center for Materials Science and Engineering, Changzhou University, Changzhou 213164, China.

出版信息

Materials (Basel). 2023 Mar 7;16(6):2149. doi: 10.3390/ma16062149.

Abstract

The welding titanium cathode roller has the obvious advantages of low cost, high efficiency, and no diameter restriction. Unfortunately, the longitudinal weld on the cathode roller adversely impacts the quality of the electrolytic copper foil due to the great difference between the microstructure of the weld zone and the base metal. Thus, it is crucial to reduce their difference by regulating the microstructure of the weld zone. In this study, a novel complex treatment of heat treatment and sandblasting is primarily developed for regulating the microstructure of the weld zone. The results show that the novel complex treatment has an efficient effect on regulating the microstructure of the weld zone and making the microstructure in the weld zone close to that of the base metal. During vacuum annealing, the microstructure of the weld zone is refined to some degree, and 650 °C annealing has the optimal effect, which can effectively reduce the ratio of α phase's length to width and reduce the microstructure difference between the weld zone and the base metal. At the same time, with an increase in the annealing temperature, the tensile strength and yield strength decreased by about 10 MPa; the elongation after fracture increased by 20%; the average microhardness of the WZ and the HAZ decreased by about 10 HV; and that of the BM decreased by about 3 HV. The heat treatment after welding can effectively adjust the properties of the weld zone, reduce the hardness and strength, and improve the toughness. The subsequent sandblasting after annealing can further refine the grain size in the weld zone and make the microstructure in the weld zone close to that of the base metal. Sandblasting after annealing can further refine the grain in the weld zone and make the microstructure in the weld zone close to that of base metal. Meanwhile, an application test confirmed that the adverse impact of a longitudinal weld on the quality of electrolytic copper foil could be resolved by adopting this novel complex treatment. Therefore, this study provides valuable technical support for the "welding" manufacturing of the titanium sleeves of the cathode roller.

摘要

焊接钛阴极辊具有成本低、效率高、无直径限制等明显优势。不幸的是,阴极辊上的纵向焊缝由于焊缝区与母材的微观结构差异巨大,对电解铜箔的质量产生不利影响。因此,通过调控焊缝区的微观结构来减小它们之间的差异至关重要。在本研究中,主要开发了一种新颖的热处理和喷砂复合处理方法来调控焊缝区的微观结构。结果表明,这种新颖的复合处理对调控焊缝区的微观结构并使焊缝区的微观结构接近母材具有显著效果。在真空退火过程中,焊缝区的微观结构得到一定程度的细化,650℃退火效果最佳,可有效降低α相的长宽比,减小焊缝区与母材之间的微观结构差异。同时,随着退火温度的升高,抗拉强度和屈服强度下降约10MPa;断后伸长率提高20%;焊缝区和热影响区的平均显微硬度下降约10HV;母材的平均显微硬度下降约3HV。焊后热处理可有效调整焊缝区的性能,降低硬度和强度,提高韧性。退火后的后续喷砂可进一步细化焊缝区的晶粒尺寸,使焊缝区的微观结构接近母材。退火后喷砂可进一步细化焊缝区的晶粒,使焊缝区的微观结构接近母材。同时,应用试验证实,采用这种新颖的复合处理方法可以解决纵向焊缝对电解铜箔质量的不利影响。因此,本研究为阴极辊钛套筒的“焊接”制造提供了有价值的技术支持。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ca27/10059315/06588fa69a16/materials-16-02149-g001.jpg

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