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基于甘蔗和库拉索纤维的生物聚乙烯复合材料:一项实验研究。

Bio-Polyethylene Composites Based on Sugar Cane and Curauá Fiber: An Experimental Study.

作者信息

Barbalho Gustavo Henrique de Almeida, Nascimento José Jefferson da Silva, Silva Lucineide Balbino da, Gomez Ricardo Soares, Farias Daniel Oliveira de, Diniz Diego David Silva, Santos Rosilda Sousa, Figueiredo Maria José de, Lima Antonio Gilson Barbosa de

机构信息

Federal Institute of Education, Science and Technology of Rio Grande do Norte, Canguaretama 58190-000, Rio Grande do Norte, Brazil.

Department of Materials Engineering, Federal University of Campina Grande, Campina Grande 58429-900, Paraiba, Brazil.

出版信息

Polymers (Basel). 2023 Mar 9;15(6):1369. doi: 10.3390/polym15061369.

Abstract

For the purpose of renewable materials applications, Curauá fiber treated with 5% sodium hydroxide was added to high-density biopolyethylene, using an entirely Brazilian raw material of sugarcane ethanol. Polyethylene grafted with maleic anhydride was used as a compatibilizer. With the addition of curauá fiber, the crystallinity was reduced, possibly due to interactions in the crystalline matrix. A positive thermal resistance effect was observed for the maximum degradation temperatures of the biocomposites. When curauá fiber was added (5% by weight), the morphology showed interfacial adhesion, greater energy storage and damping capacity. Although curauá fiber additions did not affect the yield strength of high-density bio polyethylene, its fracture toughness improved. With the addition of curauá fiber (5% by weight), the fracture strain was greatly reduced to about 52%, the impact strength was also reduced, suggesting a reinforcing effect. Concomitantly, the modulus and the maximum bending stress, as well as the Shore D hardness of the curauá fiber biocomposites (at 3 and 5% by weight), were improved. Two important aspects of product viability were achieved. First, there was no change in processability and, second, with the addition of small amounts of curauá fiber, there was a gain in the specific properties of the biopolymer. The resulting synergies can help ensure more sustainable and environmentally friendly manufacturing of automotive products.

摘要

为了可再生材料的应用,将用5%氢氧化钠处理过的库拉索纤维添加到高密度生物聚乙烯中,使用的是完全巴西原料甘蔗乙醇。用马来酸酐接枝的聚乙烯用作增容剂。随着库拉索纤维的添加,结晶度降低,这可能是由于结晶基质中的相互作用。对于生物复合材料的最大降解温度,观察到了积极的耐热性效果。当添加库拉索纤维(重量比为5%)时,形态显示出界面粘附、更大的储能和阻尼能力。尽管添加库拉索纤维并未影响高密度生物聚乙烯的屈服强度,但其断裂韧性得到了改善。随着库拉索纤维(重量比为5%)的添加,断裂应变大幅降低至约52%,冲击强度也降低,表明有增强效果。同时,库拉索纤维生物复合材料(重量比为3%和5%)的模量、最大弯曲应力以及邵氏D硬度都得到了提高。实现了产品可行性的两个重要方面。第一,加工性能没有变化;第二,添加少量库拉索纤维后,生物聚合物的特定性能有所提升。由此产生的协同效应有助于确保汽车产品的制造更具可持续性和环境友好性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b81b/10056238/0d95e748ac18/polymers-15-01369-g001.jpg

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