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用于地板应用的环氧树脂,回收废弃水泥石棉的理想载体。

Epoxy Resins for Flooring Applications, an Optimal Host for Recycling Deactivated Cement Asbestos.

作者信息

Campanale Fabrizio, Vergani Fabrizio, Marian Narcisa Mihaela, Viti Cecilia, Bianchi Alberto, Ferrario Silvia, Mauri Michele, Capitani Giancarlo

机构信息

Department of Earth and Environmental Sciences (DISAT), University of Milano-Bicocca, Piazza della Scienza 4, 20126 Milano, Italy.

Department of Physical Science, Earth, and Environment (DSFTA), University of Siena, Via Laterina 8, 53100 Siena, Italy.

出版信息

Polymers (Basel). 2023 Mar 12;15(6):1410. doi: 10.3390/polym15061410.

Abstract

Cement asbestos slates, commonly known as Eternit and still abundant in private and public buildings, were deactivated through a thermal process. The resulting deactivated cement asbestos powder (DCAP), a mixture of Ca-Mg-Al silicates and glass, was compounded with Pavatekno Gold 200 (PT) and Pavafloor H200/E (PF), two different epoxy resins (bisphenol A epichlorohydrin) for flooring applications. The addition of the DCAP filler to the PF samples causes a slight but acceptable decrease in the relevant mechanical properties (compressive, tensile, and flexural strengths) upon increasing DCAP content. The addition of the DCAP filler to pure epoxy (PT resin) causes a slight decrease in the tensile and flexural strengths with increasing DCAP content, while the compressive strength is almost unaffected, and the Shore hardness increases. The main mechanical properties of the PT samples are significantly better than those of the filler-bearing sample of normal production. Overall, these results suggest that DCAP can be advantageously used as filler in addition to, or in substitution for, commercial barite. In particular, the sample with 20 wt% of DCAP is the best performing in terms of compressive, tensile, and flexural strengths, whereas the sample with 30 wt% of DCAP shows the highest Shore hardness, which is an important property to be considered in flooring applications.

摘要

水泥石棉板,通常称为埃特尼特,在私人和公共建筑中仍然大量存在,通过热过程使其失去活性。由此产生的失活水泥石棉粉(DCAP),一种钙镁铝硅酸盐和玻璃的混合物,与两种不同的用于地板应用的环氧树脂(双酚A环氧氯丙烷)Pavatekno Gold 200(PT)和Pavafloor H200/E(PF)混合。在PF样品中添加DCAP填料,随着DCAP含量的增加,相关机械性能(抗压强度、抗拉强度和抗弯强度)会略有下降,但仍可接受。在纯环氧树脂(PT树脂)中添加DCAP填料,随着DCAP含量的增加,抗拉强度和抗弯强度略有下降,而抗压强度几乎不受影响,肖氏硬度增加。PT样品的主要机械性能明显优于正常生产的含填料样品。总体而言,这些结果表明,DCAP可以有利地用作商业重晶石的补充填料或替代填料。特别是,含20 wt%DCAP的样品在抗压强度、抗拉强度和抗弯强度方面表现最佳,而含30 wt%DCAP的样品显示出最高的肖氏硬度,这是地板应用中需要考虑的一项重要性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/57a0/10056465/b1faa211539c/polymers-15-01410-g001.jpg

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