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基于氧化锑的碱金属离子存储用阳极材料。

Antimony Oxides-Based Anode Materials for Alkali Metal-Ion Storage.

机构信息

Key Laboratory of Eco-functional Polymer Materials of the Ministry of Education, Key laboratory of Eco-environmental Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, 967 Anning East Road, Lanzhou, Gansu Province, 730070, China.

School of Engineering, Westlake University, 18 Shilongshan Road, Hangzhou, 310024, Zhejiang Province, China.

出版信息

Chemistry. 2023 Jun 19;29(34):e202300506. doi: 10.1002/chem.202300506. Epub 2023 May 2.

Abstract

With the increasing demand for renewable energy, alkali metal-ion (lithium/sodium/potassium-ion) batteries play more and more important roles in the field of static storage and electrical vehicle industry. Novel anode materials with high reversible capacity, safety and long-term cycling stability are desiderated to meet the ever-growing demand for alkali metal-ion batteries with high electrochemical performance. Antimony oxides (Sb O ) show electrochemical reaction activity with all of lithium, sodium and potassium, and are expected to be promising anode materials for alkali metal-ion storage due to their high theoretical capacities, appropriate operating potential and excellent safety properties. This review is devoted to overview the research progress on reaction mechanism and improvements in electrochemical performance of antimony oxides for alkali metal-ion storage, and look forward to their further prospects.

摘要

随着对可再生能源需求的不断增加,碱金属离子(锂离子/钠离子/钾离子)电池在静态存储和电动汽车行业中发挥着越来越重要的作用。具有高可逆容量、安全性和长期循环稳定性的新型阳极材料,以满足对具有高电化学性能的碱金属离子电池的日益增长的需求。氧化锑(Sb2O3)与所有的锂、钠和钾都具有电化学反应活性,由于其具有高的理论容量、合适的工作电势和优异的安全性能,有望成为用于碱金属离子存储的有前途的阳极材料。本综述致力于概述氧化锑用于碱金属离子存储的反应机制和电化学性能改进的研究进展,并展望其进一步的前景。

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