Müller Carsten, Schu Justin, Morgenstern Bernd, Zimmer Michael, Schmidtmann Marc, Schäfer André
Faculty of Natural Sciences and Technology, Department of Chemistry, Saarland University 66123 Saarbrücken Germany
School of Mathematics and Science, Institute of Chemistry, Carl von Ossietzky University of Oldenburg 26129 Oldenburg Germany.
RSC Adv. 2023 Mar 31;13(15):10249-10253. doi: 10.1039/d3ra01384g. eCollection 2023 Mar 27.
Phosphanyl-substituted tin(ii) half sandwich complexes are reported. Due to the Lewis acidic tin center and Lewis basic phosphorous atom they form head-to-tail dimers. Their properties and reactivities were investigated both experimentally and theoretically. Furthermore, related transition metal complexes of these species are presented.
报道了膦基取代的二价锡半夹心配合物。由于路易斯酸性的锡中心和路易斯碱性的磷原子，它们形成头对尾二聚体。对它们的性质和反应活性进行了实验和理论研究。此外，还介绍了这些物种的相关过渡金属配合物。
