Yang Qiqi, Liu Yamei, Xiang Luoxing, Zhang Jiacheng, Yin Yucheng, Xu Fugui, Mai Yiyong
School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China.
Chem Commun (Camb). 2023 Apr 18;59(32):4742-4745. doi: 10.1039/d3cc00481c.
This work demonstrates a universal approach, based on the self-assembly of block copolymers, for the synthesis of novel conjugated microporous polymers (CMPs) with bicontinuous mesostructures. Three hexaazatriphenylene (Aza)-fused CMPs (Aza-CMPs) with double diamond structures were synthesized. The study broadens the spectrum of bicontinuous porous materials and opens a new route for synthesizing CMPs with new topologies.
这项工作展示了一种基于嵌段共聚物自组装的通用方法，用于合成具有双连续介观结构的新型共轭微孔聚合物（CMP）。合成了三种具有双菱形结构的六氮杂三亚苯（Aza）稠合CMP（Aza-CMP）。该研究拓宽了双连续多孔材料的范围，并为合成具有新拓扑结构的CMP开辟了一条新途径。
