Radiobiology Department, National Veterinary Research Institute, NRL for Halogenated POPs (PCDD/Fs, PCBs and PBDE) in Food and Feed, 57 Partyzantow Avenue, 24-100, Pulawy, Poland.
Environ Sci Pollut Res Int. 2023 May;30(21):59596-59605. doi: 10.1007/s11356-023-26626-w. Epub 2023 Apr 3.
Perfluoroalkyl substances (PFASs) were investigated in five Baltic fish species (sprat, herring, salmon, trout, and cod). Each species' median lower bound (LB) concentration of ∑14 PFASs was as follows: in sprat it was 3.54 µg/kg wet weight (w.w.), in cod 2.15 µg/kg w.w., in salmon 2.10 µg/kg w.w., in trout 2.03 µg/kg w.w. and in herring 1.74 µg/kg w.w.. Regarding the species' median LB of ∑4 PFASs (perfluorooctane sulfonic acid (PFOS), perfluorooctanoic acid (PFOA), perfluorononanoic acid (PFNA), and perfluorohexane sulfonic acid (PFHxS)), sprat was the most contaminated with 2.90 µg/kg w.w. and herring was the least with 1.17 µg/kg w.w.. Among all PFASs, PFOS was found in the highest concentrations (range 0.04-9.16 µg/kg w.w.) and the percentage share in the total concentration of ∑14 PFASs was between 56 and 73%. The average proportion of linear PFOS (L-PFOS) in the total PFOS (branched and linear) was the highest in salmon at 89% and trout at 87%, and in the other three species it ranged from 75 to 80%. Different consumption scenarios were assumed and the intake of PFASs was calculated for children and adults. Dietary intake via fish consumption was 3.20-25.13 ng/kg of body weight (b.w.) for children and 1.68-8.30 ng/kg b.w. for adults. Baltic fish caught along Polish coastal areas are a significant source of PFASs, especially for children.
全氟烷基物质（PFASs）在五种波罗的海鱼类（鲱鱼、鲱鱼、三文鱼、鳟鱼和鳕鱼）中进行了研究。每种鱼类∑14PFASs 的中位数下限（LB）浓度如下：鲱鱼为 3.54μg/kg 湿重（w.w.），鳕鱼为 2.15μg/kg w.w.，三文鱼为 2.10μg/kg w.w.，鳟鱼为 2.03μg/kg w.w.，鲱鱼为 1.74μg/kg w.w.。关于物种∑4PFASs（全氟辛烷磺酸（PFOS）、全氟辛酸（PFOA）、全氟壬酸（PFNA）和全氟己烷磺酸（PFHxS））的中位数 LB，鲱鱼污染最严重，为 2.90μg/kg w.w.，而鲱鱼污染最少，为 1.17μg/kg w.w.。在所有 PFASs 中，PFOS 的浓度最高（范围为 0.04-9.16μg/kg w.w.），占∑14PFASs 总浓度的百分比在 56%至 73%之间。总 PFOS（支链和线性）中线性 PFOS（L-PFOS）的平均比例在三文鱼中最高，为 89%，在鳟鱼中最高，为 87%，而在其他三种鱼类中，其比例范围为 75%至 80%。假设了不同的消费情景，并计算了儿童和成人对 PFASs 的摄入量。通过鱼类消费摄入的 PFASs 量为儿童 3.20-25.13ng/kg 体重（b.w.），成人 1.68-8.30ng/kg b.w.。在波兰沿海地区捕获的波罗的海鱼类是 PFASs 的重要来源，尤其是对儿童而言。
