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冠醚盐掺杂梯型导电聚合物用于制备空气稳定的 n 型热电材料。

Crown ether salt-doped ladder-type conducting polymers for air-stable n-type thermoelectric materials.

机构信息

Faculty of Materials Science and Engineering, Kyoto Institute of Technology, Kyoto 606-8585, Japan.

Material Innovation Research Center (MIRC) and Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan.

出版信息

Chem Commun (Camb). 2023 May 4;59(37):5531-5534. doi: 10.1039/d3cc00840a.

Abstract

Thermoelectric energy harvesters based on p- and n-type organic semiconductors are in high demand, while the air stability of n-type devices has long been a challenge. Here, we demonstrate that supramolecular salt-functionalized n-doped ladder-type conducting polymers exhibit excellent stability in the presence of dry air.

摘要

基于 p 型和 n 型有机半导体的热电能量收集器需求量很大,而 n 型器件的空气稳定性一直是一个挑战。在这里,我们证明了超分子盐功能化的 n 掺杂梯形导电聚合物在干燥空气中表现出优异的稳定性。

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