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有机热电材料:新兴绿色能源材料,可直接高效地将热能转化为电能。

Organic thermoelectric materials: emerging green energy materials converting heat to electricity directly and efficiently.

机构信息

Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China; University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.

出版信息

Adv Mater. 2014 Oct 29;26(40):6829-51. doi: 10.1002/adma.201305371. Epub 2014 Mar 31.

Abstract

The abundance of solar thermal energy and the widespread demands for waste heat recovery make thermoelectric generators (TEGs) very attractive in harvesting low-cost energy resources. Meanwhile, thermoelectric refrigeration is promising for local cooling and niche applications. In this context there is currently a growing interest in developing organic thermoelectric materials which are flexible, cost-effective, eco-friendly and potentially energy-efficient. In particular, the past several years have witnessed remarkable progress in organic thermoelectric materials and devices. In this review, thermoelectric properties of conducting polymers and small molecules are summarized, with recent progresses in materials, measurements and devices highlighted. Prospects and suggestions for future research efforts are also presented. The organic thermoelectric materials are emerging candidates for green energy conversion.

摘要

太阳能的丰富性和广泛的余热回收需求使得热电发电机(TEG)在利用低成本能源方面极具吸引力。同时,热电制冷在局部冷却和利基应用方面也很有前景。在这种情况下,人们对开发有机热电材料越来越感兴趣,这些材料具有柔韧性、成本效益、环保性和潜在的节能性。特别是,过去几年有机热电材料和器件取得了显著进展。在这篇综述中,总结了导电聚合物和小分子的热电性能,并强调了材料、测量和器件方面的最新进展。还提出了对未来研究工作的展望和建议。有机热电材料是绿色能源转换的新兴候选材料。

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