通过轮烷取向异构体包封来选择性增强有机染料的性质。
Selective enhancement of organic dye properties through encapsulation in rotaxane orientational isomers.
机构信息
Dipartimento di Chimica Industriale "Toso Montanari", Università di Bologna, viale del Risorgimento 4, 40136 Bologna, Italy.
Center for Light-Activated Nanostructures (CLAN), Università di Bologna and Consiglio Nazionale delle Ricerche, via Gobetti 101, 40129 Bologna, Italy.
出版信息
Chem Commun (Camb). 2023 Apr 20;59(33):4970-4973. doi: 10.1039/d3cc01135f.
We report the synthesis and characterisation of [2]rotaxanes based on a stilbazolium dye and a calix[6]arene macrocycle. Since both components are non-symmetric, two orientational isomers are obtained. The two isomers display distinct photophysical and photochemical properties in solution and solid state, superior to the unencapsulated dye.
我们报告了基于芴酮染料和杯[6]芳烃大环的[2]轮烷的合成与表征。由于两个组成部分都是不对称的，因此得到了两种取向异构体。这两种异构体在溶液和固态中表现出不同的光物理和光化学性质，优于未封装的染料。
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