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了解果胶物理化学性质变化对热加工和贮藏过程中模拟美拉德反应体系褐变的影响。

Understanding the impact of pectin physicochemical variation on browning of simulated Maillard reaction system in thermal and storage processing.

机构信息

Institute of Food Science and Technology, CAAS, Key Laboratory of Agro-Products Processing, Ministry of Agriculture and Rural Affairs of the People's Republic of China, Beijing 100193, China.

Institute of Food Science and Technology, CAAS, Key Laboratory of Agro-Products Processing, Ministry of Agriculture and Rural Affairs of the People's Republic of China, Beijing 100193, China.

出版信息

Int J Biol Macromol. 2023 Jun 15;240:124347. doi: 10.1016/j.ijbiomac.2023.124347. Epub 2023 Apr 5.

Abstract

Maillard reaction browning is one of the quality deterioration in dried fruit products, but how pectin affects Maillard reaction in the fruit drying and storage process is not clear. This study aimed at investigating the mechanism of pectin variation impact on the browning of Maillard reaction by using simulated system (l-lysine, d-fructose and pectin) in thermal (60 °C and 90 °C for 8 h) and storage (37 °C for 14 days) process. Results showed that apple pectin (AP) and sugar beet pectin (SP) significantly enhanced the browning index (BI) of the Maillard reaction system by 0.01 to 134.51 in the thermal and storage processes, respectively, which were methylation degree of pectin-dependent. The pectin depolymerization product participated Maillard reaction by reacting with l-lysine, and increasing the 5-hydroxymethyl furfural (5-HMF) content (1.25-11.41-fold) and Abs (0.01-0.09). It also produced a new product (m/z 225.1245), which finally increased browning level of the system.

摘要

美拉德反应褐变是干制水果制品品质劣化的原因之一,但果胶如何影响水果干制和贮藏过程中的美拉德反应尚不清楚。本研究旨在通过使用模拟体系(l-赖氨酸、d-果糖和果胶)在热(60°C 和 90°C 8 h)和贮藏(37°C 14 天)过程中,研究果胶变化对美拉德反应褐变的影响机制。结果表明,苹果果胶(AP)和糖甜菜果胶(SP)分别在热和贮藏过程中使美拉德反应体系的褐变指数(BI)显著增加了 0.01 到 134.51,这与果胶的甲基化程度有关。果胶解聚产物通过与 l-赖氨酸反应参与美拉德反应,增加 5-羟甲基糠醛(5-HMF)含量(1.25-11.41 倍)和吸光度(0.01-0.09)。它还产生了一种新的产物(m/z 225.1245),最终增加了体系的褐变程度。

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