可见光诱导的C（）-N键形成的最新进展。 （原文中括号处内容缺失）
Recent advances in visible light-induced C( )-N bond formation.
作者信息
Rivas Mónica, Palchykov Vitalii, Jia Xiangqing, Gevorgyan Vladimir
机构信息
Department of Chemistry and Biochemistry, The University of Texas at Dallas, Richardson, TX, USA.
Department of Biochemistry, The University of Texas Southwestern Medical Center, Dallas, TX, USA.
出版信息
Nat Rev Chem. 2022 Aug;6(8):544-561. doi: 10.1038/s41570-022-00403-8. Epub 2022 Jul 11.
Abstract
Synthetic chemists have long focused on selective C( )-N bond-forming approaches in response to the high value of this motif in natural products, pharmaceutical agents and functional materials. In recent years, visible light-induced protocols have become an important synthetic platform to promote this transformation under mild reaction conditions. These photo-driven methods rely on converting visible light into chemical energy to generate reactive but controllable radical species. This Review highlights recent advances in this area, mostly after 2014, with an emphasis placed on C( )-H bond activations, including amination of olefins and carbonyl compounds, and cross-coupling reactions.
摘要
长期以来，合成化学家一直专注于选择性C（）-N键形成方法，因为该结构单元在天然产物、药物制剂和功能材料中具有很高的价值。近年来，可见光诱导的反应方案已成为在温和反应条件下促进这种转化的重要合成平台。这些光驱动方法依靠将可见光转化为化学能来产生活性但可控的自由基物种。本综述重点介绍了该领域（主要是2014年之后）的最新进展，重点是C（）-H键活化，包括烯烃和羰基化合物的胺化反应以及交叉偶联反应。
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