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盐水老化对磁流变弹性体力学和流变性能的影响。

The effect of salt water ageing on the mechanical and rheological properties of magnetorheological elastomer.

机构信息

Engineering Materials & Structures (eMast) ikhoza, Malaysia-Japan International Institute of Technology (MJIIT), Universiti Teknologi Malaysia, 54100, Kuala Lumpur, Malaysia.

Mechanical Engineering Department, Faculty of Engineering, Universitas Sebelas Maret, J1. Ir. Sutami 36A, Ketingan, Surakarta, 57126, Central Java, Indonesia.

出版信息

Sci Rep. 2023 Apr 10;13(1):5810. doi: 10.1038/s41598-023-33171-6.

Abstract

This paper aims to investigate the mechanical and rheological properties of magnetorheological elastomer (MRE) in marine ecosystems. The prepared samples comprised silicone rubber (SR) and 70 wt% micron-sized carbonyl iron particles (CIPs), immersed in an artificial marine ecosystem using salt water (Natrium Chloride) for 30 days. The mechanical properties of MRE samples were evaluated using hardness and quasi-static tensile tests. While the rheometer was used to investigate the rheological properties of their storage modulus condition with magnetic field stimulation. Further analysis of the defects and damages caused by salt water ageing was done through morphological observation using scanning electron microscope (SEM) technology. The results showed that the hardness and tensile strength of MRE samples that were soaked in salt water were affected over time. Lower values of hardness and tensile strength were obtained after 30 days due to the presence of Na and Cl, which acted as an accelerator to the hydrolyzation process of the MRE. The process then, enhanced the water ingress capability into the matrix to cause the molecular changes. Interestingly, for rheological properties, 30 days of salt water ageing allowed the water molecules to move the MRE matrix molecular chains apart, a process known as plasticization and thus increasing the MR effect. Furthermore, morphological evidence was established to determine the MRE changes during salt water ageing. The research findings should greatly contribute to a better understanding of the effect of salt water on the performance of MRE.

摘要

本文旨在研究海洋生态系统中磁流变弹性体(MRE)的力学和流变性能。制备的样品由硅橡胶(SR)和 70wt%微米级羰基铁粉(CIP)组成,在人工海洋生态系统中使用盐水(氯化钠)浸泡 30 天。使用硬度和准静态拉伸试验评估 MRE 样品的力学性能。而流变仪则用于研究在磁场刺激下其储能模量条件的流变性能。通过扫描电子显微镜(SEM)技术进行形貌观察,进一步分析盐水老化引起的缺陷和损伤。结果表明,浸泡在盐水中的 MRE 样品的硬度和拉伸强度随时间而变化。由于存在 Na 和 Cl,它们充当了 MRE 水解过程的促进剂,30 天后硬度和拉伸强度值降低。然后,该过程增强了水进入基体的能力,导致分子发生变化。有趣的是,对于流变性能,30 天的盐水老化使水分子能够将 MRE 基体分子链分开,这一过程称为增塑作用,从而增加了磁流变效应。此外,还建立了形态学证据来确定 MRE 在盐水老化过程中的变化。研究结果应该对更好地理解盐水对 MRE 性能的影响有很大的贡献。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b92/10086040/7409643e6167/41598_2023_33171_Fig1_HTML.jpg

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