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超临界水环境中辐照12Cr铁素体-马氏体不锈钢应力腐蚀开裂抗性研究

Investigation of Stress Corrosion Cracking Resistance of Irradiated 12Cr Ferritic-Martensitic Stainless Steel in Supercritical Water Environment.

作者信息

Margolin Boris, Pirogova Natalia, Sorokin Alexander, Kokhonov Vasiliy, Dub Alexey, Safonov Ivan

机构信息

Central Research Institute of Structural Materials "Prometey" of National Research Center "Kurchatov Institute", 191015 Saint-Petersburg, Russia.

Joint-Stock Company "Science and Innovations", 115035 Moscow, Russia.

出版信息

Materials (Basel). 2023 Mar 24;16(7):2585. doi: 10.3390/ma16072585.

DOI:10.3390/ma16072585
PMID:37048889
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10095323/
Abstract

The supercritical water-cooled reactors (SWCR) belong to Generation IV of reactors. These reactors have a number of advantages over currently operating WWERs and PWRs. These advantages include higher thermal efficiency, a more simplified unit design, and the possibility of incorporating it into a closed fuel cycle. It is therefore necessary to identify candidate materials for the SWCR and validate the safety and effectiveness of their use. 12Cr ferritic-martensitic (F/M) stainless steel is considered a candidate material for SWCR internals. Radiation embrittlement and corrosion cracking in the primary circuit coolant environment are the main mechanisms of F/M steels degradation during SWCR operation. Here, the stress corrosion cracking (SCC) in supercritical water at 390 and 550 °C of 12Cr F/M steel irradiated by neutrons to 12 dpa is investigated. Autoclave tests of specially designed disk specimens in supercritical water were performed. The tests were carried out under different constant load (CL), temperature 450 °C, and pressure in autoclave 25 MPa. The threshold stress, below which the SCC initiation of irradiated 12Cr F/M steel does not occur, was determined.

摘要

超临界水冷反应堆(SWCR)属于第四代反应堆。与目前运行的压水堆和沸水堆相比,这些反应堆具有许多优势。这些优势包括更高的热效率、更简化的机组设计以及将其纳入闭式燃料循环的可能性。因此,有必要确定超临界水冷反应堆的候选材料,并验证其使用的安全性和有效性。12Cr铁素体-马氏体(F/M)不锈钢被认为是超临界水冷反应堆内部构件的候选材料。在超临界水冷反应堆运行期间,主回路冷却剂环境中的辐射脆化和腐蚀开裂是F/M钢降解的主要机制。在此,研究了中子辐照至12 dpa的12Cr F/M钢在390和550°C超临界水中的应力腐蚀开裂(SCC)情况。对专门设计的圆盘试样在超临界水中进行了高压釜试验。试验在不同的恒定载荷(CL)、450°C温度和高压釜压力25 MPa条件下进行。确定了辐照12Cr F/M钢不发生应力腐蚀开裂起始的阈值应力。

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