Effects of Additives on Electrochromic Properties of Nanocrystalline Tungsten Oxide Films Prepared by Complexation-Assisted Sol-Gel Method.

To improve the electrochromic (EC) properties of sol-gel-derived WO films, a series of organic small molecules, such as dopamine (DA), catechol, tyramine, phenol and 2-phenylethylamine, were added into peroxotungstic acid precursor sols as structure-directing additives, and five modified WO films were prepared by a simple and low-cost complexation-assisted sol-gel method. The effects of the above additives on the EC properties of the modified WO films have been studied in detail. Compared with the pure WO polycrystalline film, all the modified films combine the advantages of nanocrystalline and amorphous phases and show higher EC properties attributed to the unique nanocrystal-embedded amorphous structure. The results indicate that different additives with different numbers and types of functional groups (hydroxyl and amino groups) can change the microstructure, morphology, and thus electrochemical and EC properties of the films in various degrees. The additives, in order of their strong interactions with the sols, are DA, catechol, tyramine, phenol and 2-phenylethylamine, primarily depending on the number of hydroxyl groups. Of all the additives, DA with both catechol hydroxyl and amino groups shows the most positive effect; that is, the WO film modified with DA exhibits the best EC properties in terms of contrast, switching speed, stability, and coloration efficiency.