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在具有锰离子蜂窝层与锰离子三角形层交替排列结构的BaMn(SeO)中连续出现的短程和长程磁有序

Successive Short- and Long-Range Magnetic Ordering in BaMn(SeO) with Honeycomb Layers of Mn Ions Alternating with Triangular Layers of Mn Ions.

作者信息

Moskin Artem, Kozlyakova Ekaterina, Chung Seung Hwan, Koo Hyun-Joo, Whangbo Myung-Hwan, Vasiliev Alexander

机构信息

Department of Low Temperature Physics and Superconductivity, Lomonosov Moscow State University, Moscow 119991, Russia.

Functional Quantum Materials Laboratory, National University of Science and Technology "MISIS", Moscow 119049, Russia.

出版信息

Materials (Basel). 2023 Mar 28;16(7):2685. doi: 10.3390/ma16072685.

DOI:10.3390/ma16072685
PMID:37048977
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10095995/
Abstract

Mixed-valent BaMnMn(SeO) crystallizes in a monoclinic structure and has honeycomb layers of Mn ions alternating with triangular layers of Mn ions. We established the key parameters governing its magnetic structure by magnetization and specific heat measurements. The title compound exhibits a close succession of a short-range correlation order at = 10.1 ± 0.1 K and a long-range Néel order at = 5.7 ± 0.1 K, and exhibits a metamagnetic phase transition at with hysteresis most pronounced at low temperatures. The causes for these observations were found using the spin exchange parameters evaluated by density functional theory calculations. The title compound represents a unique case in which uniform chains of integer spin Mn ( = 2) ions interact with those of half-integer spin Mn ( = 5/2) ions.

摘要

混合价态的BaMnMn(SeO)以单斜结构结晶，具有锰离子的蜂窝层与锰离子的三角形层交替排列。我们通过磁化强度和比热测量确定了控制其磁结构的关键参数。标题化合物在10.1±0.1 K时表现出短程关联有序的紧密连续，在5.7±0.1 K时表现出长程奈尔有序，并且在某温度下表现出变磁相变，在低温下磁滞最为明显。利用密度泛函理论计算评估的自旋交换参数找到了这些观测结果的原因。标题化合物代表了一种独特的情况，即整数自旋Mn（S = 2）离子的均匀链与半整数自旋Mn（S = 5/2）离子的均匀链相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e317/10095995/9062e98e1b55/materials-16-02685-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e317/10095995/a76931958f7a/materials-16-02685-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e317/10095995/84920bddf920/materials-16-02685-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e317/10095995/23fbf9f2a586/materials-16-02685-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e317/10095995/f558ee0de23b/materials-16-02685-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e317/10095995/5d142aaf2418/materials-16-02685-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e317/10095995/325ab994c352/materials-16-02685-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e317/10095995/9062e98e1b55/materials-16-02685-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e317/10095995/a76931958f7a/materials-16-02685-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e317/10095995/84920bddf920/materials-16-02685-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e317/10095995/23fbf9f2a586/materials-16-02685-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e317/10095995/f558ee0de23b/materials-16-02685-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e317/10095995/5d142aaf2418/materials-16-02685-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e317/10095995/325ab994c352/materials-16-02685-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e317/10095995/9062e98e1b55/materials-16-02685-g007.jpg

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本文引用的文献

1
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Materials (Basel). 2022 Aug 21;15(16):5773. doi: 10.3390/ma15165773.
2
Unusual Spin Exchanges Mediated by the Molecular Anion PS: Theoretical Analyses of the Magnetic Ground States, Magnetic Anisotropy and Spin Exchanges of MPS (M = Mn, Fe, Co, Ni).PS 介导的异常自旋交换：MPS（M = Mn、Fe、Co、Ni）的磁基态、磁各向异性和自旋交换的理论分析。
Molecules. 2021 Mar 5;26(5):1410. doi: 10.3390/molecules26051410.
3
Spin Exchanges Between Transition Metal Ions Governed by the Ligand p-Orbitals in Their Magnetic Orbitals.
过渡金属离子磁轨道中配体 p 轨道控制的自旋交换。
Molecules. 2021 Jan 20;26(3):531. doi: 10.3390/molecules26030531.
4
Magnetic properties and energy-mapping analysis.磁性特性和能量映射分析。
Dalton Trans. 2013 Jan 28;42(4):823-53. doi: 10.1039/c2dt31662e.
5
Density-functional characterization of the multiferroicity in spin spiral chain cuprates.自旋螺旋链铜酸盐中多铁性的密度泛函表征
Phys Rev Lett. 2007 Dec 21;99(25):257203. doi: 10.1103/PhysRevLett.99.257203.
6
Generalized Gradient Approximation Made Simple.广义梯度近似简化法
Phys Rev Lett. 1996 Oct 28;77(18):3865-3868. doi: 10.1103/PhysRevLett.77.3865.
7
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set.使用平面波基组进行从头算总能量计算的高效迭代方案。
Phys Rev B Condens Matter. 1996 Oct 15;54(16):11169-11186. doi: 10.1103/physrevb.54.11169.
8
Projector augmented-wave method.投影增强波方法。
Phys Rev B Condens Matter. 1994 Dec 15;50(24):17953-17979. doi: 10.1103/physrevb.50.17953.