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利用磷酸盐沉淀法对樟子松进行表面处理以提高抗压强度和耐火性能

Surface Treatment of Mongolian Scots Pine Using Phosphate Precipitation for Better Performance of Compressive Strength and Fire Resistance.

作者信息

Ge Yan, Wang Liang, Wang Xuepeng, Wang Hao

机构信息

School of Civil Engineering and Architecture, Anhui University of Science and Technology, Huainan 232001, China.

出版信息

Materials (Basel). 2023 Mar 29;16(7):2711. doi: 10.3390/ma16072711.

Abstract

Wood, as a naturally green and environmentally friendly material, has been widely used in the construction and decoration industries. However, the flammability of wood poses serious safety problems. To improve the fire resistance of wood, In this study, it is proposed to use calcium chloride (CaCl) and disodium hydrogen phosphate (NaHPO, DSP) to impregnate wood for multiple cycles. The experimental results show that phosphate mineral precipitation can be deposited on the surface of the wood. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) are used to analyze the micromorphology of mineral precipitation and use the MIP test to analyze the treated wood pore structure. The results show that with the increase in the number of cycles, the phosphate deposited on the surface of the wood increases, and the cumulative pore volume and water absorption rate of the wood after 10 cycles are 54.3% and 13.75% lower than that of untreated wood respectively. In addition, the cone calorimeter (CONE) confirmed that the total heat release (THR) and total smoke production (TSP) of wood treated in 10 cycles have decreased by 48.7% and 54.2% respectively compared with the untreated wood. Hence, this treatment method not only improves the mechanical properties of wood. It also improves fire resistance.

摘要

木材作为一种天然绿色环保材料,已广泛应用于建筑和装饰行业。然而,木材的易燃性带来了严重的安全问题。为提高木材的耐火性,本研究提出使用氯化钙(CaCl)和磷酸氢二钠(NaHPO,DSP)对木材进行多次浸渍处理。实验结果表明,磷酸盐矿物沉淀可沉积在木材表面。采用扫描电子显微镜(SEM)和X射线衍射(XRD)分析矿物沉淀的微观形貌,并使用压汞法(MIP)测试分析处理后木材的孔隙结构。结果表明,随着循环次数的增加,沉积在木材表面的磷酸盐增多,10次循环后木材的累积孔隙体积和吸水率分别比未处理木材低54.3%和13.75%。此外,锥形量热仪(CONE)证实,与未处理木材相比,10次循环处理后的木材总热释放量(THR)和总产烟量(TSP)分别降低了48.7%和54.2%。因此,这种处理方法不仅提高了木材的力学性能,还提高了耐火性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/93e1/10095691/a04d4524b8c7/materials-16-02711-g001.jpg

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