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海洋潮汐区硫铝酸钙混凝土的力学性能与氯离子渗透

Mechanical Performance and Chloride Penetration of Calcium Sulfoaluminate Concrete in Marine Tidal Zone.

作者信息

Tang Xudong, Zhan Shulin, Xu Qiang, He Kui

机构信息

College of Civil Engineering and Architecture, Zhejiang University, Hangzhou 310058, China.

Ocean Academy, Zhejiang University, Zhoushan 316021, China.

出版信息

Materials (Basel). 2023 Apr 6;16(7):2905. doi: 10.3390/ma16072905.

Abstract

The enhancement of the durability of sulfoaluminate cement (CSA) in marine environments is of great importance. To this end, an investigation was carried out involving the placement of CSA concrete in the tidal zone of Zhairuoshan Island, Zhoushan, China, and subjected to a 20-month marine tidal exposure test. The comparison was made with ordinary Portland cement (OPC) concrete to evaluate the effectiveness of the former. The test findings indicate that the compressive strength of both types of concrete is reduced by seawater dry-wet cycling, and the porosity of the surface concrete is increased. However, the compressive strength of CSA concrete is observed to be more stable under long-term drying-wetting cycles. When the ettringite in the CSA surface concrete is decomposed due to carbonization and alkalinity reduction, its products will react with Ca and SO in seawater to regenerate ettringite to fill in the concrete pores, making the concrete strength more stable and hindering chlorine penetration. Furthermore, CSA concrete exhibits a higher capillary absorption capacity than OPC concrete, which results in chloride accumulation on its surface. However, the diffusion capacity of chloride in CSA concrete is significantly lower than that in OPC concrete.

摘要

提高硫铝酸盐水泥(CSA)在海洋环境中的耐久性具有重要意义。为此,在中国舟山摘箬山岛的潮间带放置了CSA混凝土,并进行了为期20个月的海洋潮汐暴露试验。将其与普通硅酸盐水泥(OPC)混凝土进行比较,以评估前者的有效性。试验结果表明,两种类型的混凝土抗压强度均因海水干湿循环而降低,表面混凝土的孔隙率增加。然而,观察到CSA混凝土的抗压强度在长期干湿循环下更稳定。当CSA表面混凝土中的钙矾石因碳化和碱度降低而分解时,其产物会与海水中的Ca和SO反应再生钙矾石以填充混凝土孔隙,使混凝土强度更稳定并阻碍氯离子渗透。此外,CSA混凝土比OPC混凝土表现出更高的毛细吸水能力,这导致其表面氯化物积累。然而,CSA混凝土中氯离子的扩散能力明显低于OPC混凝土。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32df/10095873/5d6aaec012d5/materials-16-02905-g001.jpg

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