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温度和盐度耐受型疏水缔合弱聚合物凝胶体系的制备及性能评价。

Preparation and Performance Evaluation of a Temperature and Salt Resistant Hydrophobic Associative Weak Polymer Gel System.

机构信息

School of Petroleum Engineering, Northeast Petroleum University, Daqing 163318, China.

Key Laboratory of Enhanced Oil Recovery, Northeast Petroleum University, Ministry of Education, Daqing 163318, China.

出版信息

Molecules. 2023 Mar 31;28(7):3125. doi: 10.3390/molecules28073125.

Abstract

We targeted high-temperature and highly saline old oil fields, whose environmental conditions could be attributed to the significantly high heterogeneity cause by long-term water flooding. The Huabei Oilfield was chosen as the research object. We developed a hydrophobic functional monomer-polymer with temperature and salt resistance by introducing the temperature-resistant and salt-resistant monomer NVP and a hydrophobic functional monomer into the main chain for copolymerization. We used a crosslinking agent with phenolic resin to prepare a weak gel system that showed temperature and salt resistance and investigated its temperature and salt resistance, infective property, plugging performance, liquid flow ability, micropore throat migration, and plugging characteristics. The results obtained using the infrared spectroscopy technique revealed the successful preparation of the phenolic resin crosslinker. The weak gel exhibited good temperature and salt resistance when the polymer concentration was 2000 mg/L, the cohesion ratio was 1:1.5, the additive concentration was 2000 mg/L, the reservoir temperature was 120 °C, and the injected water salinity was 40,300.86 mg/L. The average viscosity retention rate of the 90-day weak gel reached more than 80% and its microstructure was examined. The coreflow experiment results revealed that the weak gel system was characterized by good infectivity. After plugging the weak gel, the effect on the direction of the liquid flow was evident and the flow rate of the low permeability layer increased to a maximum of 48.63% under conditions of varying permeability levels. A significant improvement in the water absorption profile was achieved. The plugging was carried out through a sand-filling pipe under varying permeability conditions and the pressure measuring points in the sand-filling pipe were sucessfully pressurized. The migration ability of the weak gel was good and the blocking rate was >85%.

摘要

我们的目标是高温、高盐老油田,这些油田的环境条件可以归因于长期注水造成的显著高非均质性。选择华北油田作为研究对象。我们通过引入耐高温和耐盐单体 NVP 以及疏水性官能团单体到主链中进行共聚,开发了一种具有耐温耐盐性的疏水性功能单体-聚合物。我们使用酚醛树脂交联剂制备了一种具有耐温耐盐性的弱凝胶体系,并研究了其耐温耐盐性、感染性、封堵性能、液流能力、微孔喉道迁移和封堵特性。红外光谱技术的结果表明成功制备了酚醛树脂交联剂。当聚合物浓度为 2000mg/L、内聚比为 1:1.5、添加剂浓度为 2000mg/L、储层温度为 120°C、注入水矿化度为 40300.86mg/L 时,弱凝胶表现出良好的耐温耐盐性。90 天弱凝胶的平均粘度保留率超过 80%,并对其微观结构进行了考察。岩心流动实验结果表明,弱凝胶体系具有良好的感染性。弱凝胶封堵后,对液流方向的影响明显,在不同渗透率条件下,低渗透层的流速最高可增加 48.63%。吸水剖面得到了显著改善。在不同渗透率条件下通过填砂管进行封堵,填砂管内的压力测量点成功加压。弱凝胶的迁移能力良好,封堵率>85%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/60ef/10096368/d1062f0b0f92/molecules-28-03125-g001.jpg

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