Wang Cheng, Zhong Liguo, Liu Yigang, Han Yugui, Zhao Peng, Yuan Yujing, Han Xiaodong
Institute of Unconventional Oil and Gas Science and Technology, China University of Petroleum-Beijing, Beijing 102249, China.
China National Offshore Oil Corporation China Ltd, Tianjin Branch, Tianjin 300459, China.
ACS Omega. 2020 Sep 16;5(38):24935-24945. doi: 10.1021/acsomega.0c03762. eCollection 2020 Sep 29.
Weak gel is a kind of three-dimensional cross-linking system with low polymer concentration and appropriate cross-linking agents, dominated by intermolecular cross-linking, supplemented by intramolecular cross-linking, and with a weak cross-linking degree. In this paper, the microstructure and properties of the weak gel were observed and evaluated under different conditions. Seepage behavior experiments and parallel core displacement experiments were carried out to evaluate profile control and flooding performance of the weak gel. Under a certain polymer concentration, with the increase in cross-linker concentration, the reticular structure of the weak gel becomes more uniform and the strength of the weak gel was further enhanced. Weak gel has more retention in porous media and greater strength. The profile control and flooding performance of the weak gel are much better than those of the polymer. A field test of weak-gel flooding was successfully carried out in LD10-1 oilfield. Most of the production wells around the weak gel injection wells responded after weak-gel injection and the accumulative oil incremental oil production of the test area was 57.8 × 10 m up to December 2018.
弱凝胶是一种聚合物浓度低且含有适量交联剂的三维交联体系,以分子间交联为主,分子内交联为辅,交联程度较弱。本文对不同条件下弱凝胶的微观结构和性能进行了观察与评价。开展了渗流行为实验和平行岩心驱替实验,以评估弱凝胶的调剖和驱油性能。在一定聚合物浓度下,随着交联剂浓度的增加,弱凝胶的网状结构变得更加均匀,其强度进一步增强。弱凝胶在多孔介质中的滞留量更大,强度更高。弱凝胶的调剖和驱油性能远优于聚合物。在LD10-1油田成功开展了弱凝胶驱油现场试验。弱凝胶注入井周围的大多数生产井在注入弱凝胶后均有响应,截至2018年12月,试验区累计增油量达57.8×10立方米。