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少层黑磷改性环氧树脂的阻燃性能

Flame Retardancy of Epoxy Resins Modified with Few-Layer Black Phosphorus.

作者信息

Zhao Yongzheng, Li Yan, Li Jiaxuan, Xiao Yifan, Mu Wenmin, Wang Zhongwei, Song Liang, Yu Jinhong

机构信息

College of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, China.

College of Biology and Chemical Engineering, Qingdao Technical College, Qingdao 266555, China.

出版信息

Polymers (Basel). 2023 Mar 27;15(7):1655. doi: 10.3390/polym15071655.

DOI:10.3390/polym15071655
PMID:37050271
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10097328/
Abstract

Few-layer black phosphorus (BP)- and red phosphorus (RP)-modified diglycidyl ether of bisphenol A-based epoxy resins (EP) was prepared with 4,4'-diaminodiphenylsulfone as a curing agent. The thermal stability and flame-retardant properties of the modified EPs were compared. Both BP and RP were able to improve the flame-retardant properties of EPs, while the BP showed higher flame-retardant efficiency than RP. As a two-dimensional nanomaterial, BP exhibited good compatibility, high flame-retardant efficiency, and negligible impact on the mechanical and thermal stability of EP. Pyrolysis-gas Fourier-transform infrared spectroscopic analysis of EP showed that the addition of BP significantly inhibited the release of pyrolysis products in the gas phase. The modes of action for flame-retardant BPs in gas phase and condensed phase were proposed.

摘要

以4,4'-二氨基二苯砜为固化剂，制备了少层黑磷（BP）和红磷（RP）改性的双酚A基环氧树脂（EP）。比较了改性环氧树脂的热稳定性和阻燃性能。BP和RP均能提高环氧树脂的阻燃性能，而BP的阻燃效率高于RP。作为一种二维纳米材料，BP表现出良好的相容性、高阻燃效率，并且对环氧树脂的机械和热稳定性影响可忽略不计。对环氧树脂进行热解气相傅里叶变换红外光谱分析表明，BP的加入显著抑制了气相中热解产物的释放。提出了阻燃BP在气相和凝聚相中的作用模式。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/d2b1b48c069c/polymers-15-01655-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/7bb45937c8e7/polymers-15-01655-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/4674b2c319c6/polymers-15-01655-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/f850181dc98c/polymers-15-01655-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/24df16eb576a/polymers-15-01655-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/289641c1e56e/polymers-15-01655-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/9a5b5fe27b0d/polymers-15-01655-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/b88f79f7265d/polymers-15-01655-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/96284a21c544/polymers-15-01655-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/e076ae12f3e6/polymers-15-01655-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/d2b1b48c069c/polymers-15-01655-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/7bb45937c8e7/polymers-15-01655-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/4674b2c319c6/polymers-15-01655-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/f850181dc98c/polymers-15-01655-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/24df16eb576a/polymers-15-01655-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/289641c1e56e/polymers-15-01655-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/9a5b5fe27b0d/polymers-15-01655-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/b88f79f7265d/polymers-15-01655-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/96284a21c544/polymers-15-01655-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/e076ae12f3e6/polymers-15-01655-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b76d/10097328/d2b1b48c069c/polymers-15-01655-g010.jpg

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本文引用的文献

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