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玄武岩和凯夫拉编织织物的混合热塑性复合材料:力学和热机械性能的比较分析

Hybrid Thermoplastic Composites from Basalt- and Kevlar-Woven Fabrics: Comparative Analysis of Mechanical and Thermomechanical Performance.

作者信息

Jamshaid Hafsa, Mishra Rajesh Kumar, Chandan Vijay, Nazari Shabnam, Shoaib Muhammad, Bizet Laurent, Jirku Petr, Muller Miroslav, Choteborsky Rostislav

机构信息

School of Engineering and Technology, National Textile University, Faisalabad 37610, Pakistan.

Department of Material Science and Manufacturing Technology, Faculty of Engineering, Czech University of Life Sciences Prague, Kamycka 129, 165 00 Prague, Czech Republic.

出版信息

Polymers (Basel). 2023 Mar 31;15(7):1744. doi: 10.3390/polym15071744.

Abstract

Current research deals with thermoplastic polyamide (PA6)-based composites reinforced with basalt and Kevlar fabrics. Hybrid composites were developed by altering the stacking sequence of basalt and two kinds of Kevlar fabrics. Pure-basalt- and pure-Kevlar-based samples were also developed for comparison purposes. The developed samples were evaluated with respect to mechanical and thermomechanical properties. Mechanical tests, e.g., tensile, flexural, and impact strength, were conducted along with thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) to ascertain the load-bearing and high-temperature stability of the hybrid composite samples vis-à-vis pure-basalt- and Kevlar-based samples. Scanning electron microscopy (SEM) was carried out to study the nature of fracture and failure of the composite samples. The pure-basalt-based PA6 thermoplastic composites exhibited the best mechanical performance. Hybridization with basalt proved to be beneficial for improving the mechanical performance of the composites using Kevlar fabrics. However, a proper stacking sequence and density of Kevlar fabric has to be selected. The thermogravimetric analysis showed minimal weight loss for basalt-based composites. Furthermore, the thermal stability of the composites using Kevlar fabric was improved by hybridization with basalt fabric. The thermomechanical characteristics of hybrid composites may be altered by changing the stacking order of the reinforcements. Differential scanning calorimetry further established that the hybrid composites with alternate layers of basalt and Kevlar can improve the heat flow rate and enable survivability at extreme temperatures. Such novel hybrid composites can be used for high-load-bearing and high-temperature applications, e.g., defense, aerospace, automotives, and energy applications.

摘要

当前的研究涉及以玄武岩和凯夫拉纤维织物增强的热塑性聚酰胺(PA6)基复合材料。通过改变玄武岩和两种凯夫拉纤维织物的堆叠顺序来制备混杂复合材料。还制备了纯玄武岩基和纯凯夫拉基样品用于对比。对制备的样品进行了力学和热机械性能评估。进行了拉伸、弯曲和冲击强度等力学测试以及热重分析(TGA)和差示扫描量热法(DSC),以确定混杂复合材料样品相对于纯玄武岩基和凯夫拉基样品的承载能力和高温稳定性。进行扫描电子显微镜(SEM)分析以研究复合材料样品的断裂和破坏性质。纯玄武岩基PA6热塑性复合材料表现出最佳的力学性能。事实证明,与玄武岩混杂有利于提高使用凯夫拉纤维织物的复合材料的力学性能。然而,必须选择合适的凯夫拉纤维织物堆叠顺序和密度。热重分析表明,玄武岩基复合材料的重量损失最小。此外,与玄武岩织物混杂提高了使用凯夫拉纤维织物的复合材料的热稳定性。通过改变增强材料的堆叠顺序,可以改变混杂复合材料的热机械特性。差示扫描量热法进一步证实,具有交替玄武岩层和凯夫拉层的混杂复合材料可以提高热流率,并使其在极端温度下具有生存能力。这种新型混杂复合材料可用于高承载和高温应用,例如国防、航空航天、汽车和能源应用。

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