Chrono-colorimetric sensor array for detection and discrimination of halide ions using an all-in-one plasmonic sensor element.

Most nanoparticle based colorimetric sensor array utilize several sensor elements and static response for discrimination of target analytes. This approach can be complicated and costly to synthesize or functionalize different nanoparticles for providing wide color variation. Herein, triangular silver nanoparticles (TSNPs) were used to develop a colorimetric sensor array by time-dimension responses. The principle of this sensor array is based on the diverse etching process of TSNPs in the presence of three halide ions, including bromide (Br), iodide (I) and chloride (Cl). Various etchings of TSNPs induced color changes at different reaction time intervals, which produced a colorimetric pattern for each ion. Therefore, using time dependent etching responses of TSNPs as a single sensing component can produce a wide color variation which can be distinguished by naked eyes. The colorimetric responses of TSNPs upon the addition of different concentrations of halide ions have been analyzed by PLS regression (PLS-R) and PLS discriminant analysis (PLS-DA). The analytical figures of merit confirmed that the developed chrono-colorimetric TSNPs -based sensor array is successful in both the discrimination and quantitative detection of halide ions. At the final step, the three halide ions were accurately determined in a real water sample, which verified the potential of the developed sensor in a real sample.