Xiamen Key Laboratory of Fire Retardant Materials, Key Laboratory of High Performance Ceramic Fibers of Education, College of Materials, Xiamen University, Xiamen, 361005, P. R. China.
Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, P. R. China.
Chemistry. 2023 Jun 27;29(36):e202300914. doi: 10.1002/chem.202300914. Epub 2023 May 5.
Exploration of organometallic metallacycles has led to the development of various polycyclic compounds with fascinating structures, which could be used as functional materials. In this work, a new rhenanaphthalene isomer was isolated from the reaction of ReH (PMe Ph) with o-ethynylphenyl alkyne in the presence of excess HCl. Its structure was then identified using the single-crystal X-ray diffraction and NMR spectroscopy. DFT studies suggest that its formation involves two protonation reactions and two migration reactions. This new rhenanaphthalene isomer enriches the family of metallacycles.
金属有机茂金属配合物的探索导致了各种具有迷人结构的多环化合物的发展，这些化合物可用作功能材料。在这项工作中，ReH(PMePh)与过量 HCl 存在下与 o-乙炔基苯基炔反应，从反应中分离出一种新的苊并萘异构体。然后使用单晶 X 射线衍射和 NMR 光谱对其结构进行了鉴定。DFT 研究表明，其形成涉及两个质子化反应和两个迁移反应。这种新的金属茂异构体丰富了金属茂环家族。
