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淡化水水质提升的评估与策略

Evaluation and strategy for improving the quality of desalinated water.

作者信息

Chowdhury Shakhawat

机构信息

Department of Civil and Environmental Engineering, King Fahd University of Petroleum & Minerals, Dhahran, 31261, Saudi Arabia.

Memorial University of Newfoundland, St. John's, NL, A1B 3X5, Canada.

出版信息

Environ Sci Pollut Res Int. 2023 May;30(24):65947-65962. doi: 10.1007/s11356-023-27180-1. Epub 2023 Apr 24.

Abstract

Seawater desalination is practiced in many coastal countries, which is accepted as clean water by the general populations. The untreated seawater reported high concentrations of bromide (50,000 - 80,000 µg/L) and iodide (21 - 60 µg/L) ions, which are reduced to non-detectable levels during thermal desalination while the concentrations of bromide and iodide ions were reduced to 250-600 µg/L and < 4-16 µg/L, respectively during reverse osmosis processes. During the treatment and/or disinfection, many brominated and iodinated disinfection byproducts (Br-DBPs and I-DBPs) are formed in desalinated water, some of which are genotoxic and cytotoxic to the mammalian cells and possible/probable human carcinogens. In this paper, DBPs' formation in desalinated and blended water from source to tap, toxicity to the mammalian cells, their risks to humans and the strategies to control DBPs were investigated. The lifetime excess cancer risks from groundwater, and desalinated and blended water sourced DBPs were 4.15 × 10 (4.72 × 10 - 1.30 × 10), 1.75 × 10 (2.58 × 10 - 5.25 × 10) and 2.59 × 10 (4.02 × 10 - 8.35 × 10) respectively, indicating higher risks from desalinated and blended water (2.56 and 4.51 times respectively) than groundwater systems. Few emerging DBPs in desalinated/blended water showed higher cyto- and genotoxicity in the mammalian cells. The findings were compared with safe drinking water standards and strategies to produce cleaner desalinated water were demonstrated.

摘要

许多沿海国家都在进行海水淡化,淡化后的水被大众视为清洁水。未经处理的海水中溴化物(50,000 - 80,000微克/升)和碘化物(21 - 60微克/升)离子浓度较高,在热法海水淡化过程中这些离子会降至检测不到的水平,而在反渗透过程中,溴化物和碘化物离子浓度分别降至250 - 600微克/升和<4 - 16微克/升。在处理和/或消毒过程中,淡化水中会形成许多溴化和碘化消毒副产物(Br-DBPs和I-DBPs),其中一些对哺乳动物细胞具有遗传毒性和细胞毒性,并且可能是人类致癌物。本文研究了从水源到水龙头的淡化水和混合水中消毒副产物的形成、对哺乳动物细胞的毒性、对人类的风险以及控制消毒副产物的策略。来自地下水、淡化水和混合水的消毒副产物导致的终生超额癌症风险分别为4.15×10(4.72×10 - 1.30×10)、1.75×10(2.58×10 - 5.25×10)和2.59×10(4.02×10 - 8.35×10),这表明淡化水和混合水带来的风险(分别为2.56倍和4.51倍)高于地下水系统。淡化水/混合水中很少有新出现的消毒副产物对哺乳动物细胞表现出更高的细胞毒性和遗传毒性。将这些研究结果与安全饮用水标准进行了比较,并展示了生产更清洁淡化水的策略。

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