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Spectrochim Acta A Mol Biomol Spectrosc. 2021 May 5;252:119475. doi: 10.1016/j.saa.2021.119475. Epub 2021 Jan 16.
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使用近红外光谱结合A-CARS-PLS法测定玉米蛋白质含量

Determination of corn protein content using near-infrared spectroscopy combined with A-CARS-PLS.

作者信息

Wu Xiaohong, Zeng Shupeng, Fu Haijun, Wu Bin, Zhou Haoxiang, Dai Chunxia

机构信息

School of Electrical and Information Engineering, Jiangsu University, Zhenjiang 212013, China.

High-Tech Key Laboratory of Agricultural Equipment and Intelligence of Jiangsu Province, Jiangsu University, Zhenjiang 212013, China.

出版信息

Food Chem X. 2023 Mar 30;18:100666. doi: 10.1016/j.fochx.2023.100666. eCollection 2023 Jun 30.

DOI:10.1016/j.fochx.2023.100666
PMID:37096170
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10121631/
Abstract

In order to quickly and accurately determine the protein content of corn, a new characteristic wavelength selection algorithm called anchor competitive adaptive reweighted sampling (A-CARS) was proposed in this paper. This method first lets Monte Carlo synergy interval PLS (MC-siPLS) to select the sub-intervals where the characteristic variables exist and then uses CARS to screen the variables further. A-CARS-PLS was compared with 6 methods, including 3 feature variable selection methods (GA-PLS, random frog PLS, and CARS-PLS) and 2 interval partial least squares methods (siPLS and MWPLS). The results showed that A-CARS-PLS was significantly better than other methods with the results: RMSECV = 0.0336, R  = 0.9951 in the calibration set; RMSEP = 0.0688, R  = 0.9820 in the prediction set. Furthermore, A-CARS reduced the original 700-dimensional variable to 23 variables. The results showed that A-CARS-PLS was better than some wavelength selection methods, and it has great application potential in the non-destructive detection of protein content in corn.

摘要

为了快速准确地测定玉米的蛋白质含量,本文提出了一种新的特征波长选择算法——锚定竞争自适应重加权采样(A-CARS)。该方法首先让蒙特卡罗协同区间偏最小二乘法(MC-siPLS)选择存在特征变量的子区间,然后使用CARS进一步筛选变量。将A-CARS-PLS与6种方法进行了比较,包括3种特征变量选择方法(GA-PLS、随机蛙跳PLS和CARS-PLS)和2种区间偏最小二乘法(siPLS和MWPLS)。结果表明,A-CARS-PLS明显优于其他方法,在校准集中的结果为:RMSECV = 0.0336,R = 0.9951;在预测集中的结果为:RMSEP = 0.0688,R = 0.9820。此外,A-CARS将原始的700维变量减少到了23个变量。结果表明,A-CARS-PLS优于一些波长选择方法,在玉米蛋白质含量无损检测中具有很大的应用潜力。