School of Chemical and Energy Engineering, Faculty of Engineering, Universiti Teknologi Malaysia, 81310, Skudai, Johor, Malaysia.
Centre of Lipids Engineering and Applied Research (CLEAR), Ibnu Sina Institute for Scientific and Industrial Research (ISI-SIR), Universiti Teknologi Malaysia, 81310, Skudai, Johor, Malaysia.
Environ Sci Pollut Res Int. 2023 May;30(25):66445-66472. doi: 10.1007/s11356-023-26951-0. Epub 2023 Apr 27.
Waste electrical and electronic equipment or e-waste has recently emerged as a significant global concern. This waste contains various valuable metals, and via recycling, it could become a sustainable resource of metals (viz. copper, silver, gold, and others) while reducing reliance on virgin mining. Copper and silver with their superior electrical and thermal conductivity have been reviewed due to their high demand. Recovering these metals will be beneficial to attain the current needs. Liquid membrane technology has appeared as a viable option for treating e-waste from various industries as a simultaneous extraction and stripping process. It also includes extensive research on biotechnology, chemical and pharmaceutical, environmental engineering, pulp and paper, textile, food processing, and wastewater treatment. The success of this process depends more on the selection of organic and stripping phases. In this review, the use of liquid membrane technology in treating/recovering copper and silver from industrial e-waste leached solutions was highlighted. It also assembles critical information on the organic phase (carrier and diluent) and stripping phase in liquid membrane formulation for selective copper and silver. In addition, the utilization of green diluent, ionic liquids, and synergist carrier was also included since it gained prominence attention latterly. The future prospects and challenges of this technology were also discussed to ensure the industrialization of technology. Herein, a potential process flowchart for the valorization of e-waste is also proposed.
电子废物或电子垃圾最近成为一个全球性的重大问题。这种废物含有各种有价值的金属,通过回收,它可以成为金属的可持续资源(如铜、银、金等),同时减少对原始矿山的依赖。由于需求较高,铜和银因其优异的导电性和导热性而受到了审查。回收这些金属将有助于满足当前的需求。液膜技术已成为处理来自各个行业的电子废物的一种可行选择,因为它是一种同时进行萃取和反萃的过程。它还包括对生物技术、化学和制药、环境工程、纸浆和造纸、纺织、食品加工和废水处理的广泛研究。该过程的成功更多地取决于有机相和反萃相的选择。在这篇综述中,强调了液膜技术在处理/从工业电子废物浸出液中回收铜和银方面的应用。它还汇集了液膜配方中用于选择性萃取铜和银的有机相(载体和稀释剂)和反萃相的关键信息。此外,还包括了绿色稀释剂、离子液体和协同载体的利用,因为它们最近受到了关注。还讨论了该技术的未来前景和挑战,以确保技术的工业化。本文还提出了电子废物增值的潜在工艺流程。