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一种自清洁 TiO<sub>2</sub>细菌纤维素超亲水水下超疏油复合膜,用于高效油水分离。

A Self-Cleaning TiO Bacterial Cellulose Super-Hydrophilic Underwater Super-Oleophobic Composite Membrane for Efficient Oil-Water Separation.

机构信息

School of Environmental Science and Engineering, Changzhou University, Changzhou 213164, China.

出版信息

Molecules. 2023 Apr 12;28(8):3396. doi: 10.3390/molecules28083396.

DOI:10.3390/molecules28083396
PMID:37110633
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10141678/
Abstract

Due to the increasingly serious problem of offshore oil spills, research related to oil-water separation has attracted more and more attention. Here, we prepared a super-hydrophilic/underwater super-oleophobic membrane (hereinafter referred to as BTA) using poly-dopamine (PDA) to adhesive TiO nanoparticles on the surface of bacterial cellulose, coated with sodium alienate by vacuum-assisted filtration technique. This demonstrates its excellent underwater super-oleophobic property. Its contact angle is about 153°. Remarkably, BTA has 99% separation efficiency. More importantly, BTA still showed excellent anti-pollution property under ultraviolet light after 20 cycles. BTA has the advantages of low cost, environmentally friendliness and good anti-fouling performance. We believe it can play an important role in dealing with problems related to oily wastewater.

摘要

由于海上溢油问题日益严重,与油水分离相关的研究越来越受到关注。在这里,我们使用聚多巴胺(PDA)将 TiO2 纳米粒子粘在细菌纤维素表面,制备了超亲水/水下超疏油膜(以下简称 BTA),然后通过真空辅助过滤技术涂覆了偏硅酸钠。这证明了它具有优异的水下超疏油性。其接触角约为 153°。值得注意的是,BTA 的分离效率达到了 99%。更重要的是,BTA 在经过 20 次循环后,在紫外光下仍表现出优异的抗污染性能。BTA 具有成本低、环保和良好的抗污性能等优点。我们相信它可以在处理含油废水相关问题方面发挥重要作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/6df27a1ee5eb/molecules-28-03396-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/6148dd3da852/molecules-28-03396-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/26d99847b091/molecules-28-03396-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/4176ba6f6afb/molecules-28-03396-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/e3eae45e5c99/molecules-28-03396-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/48e4b7185f37/molecules-28-03396-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/80c94fa6b934/molecules-28-03396-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/6e69901ac5d6/molecules-28-03396-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/5a3b26f8828c/molecules-28-03396-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/203fb544e093/molecules-28-03396-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/6df27a1ee5eb/molecules-28-03396-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/6148dd3da852/molecules-28-03396-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/26d99847b091/molecules-28-03396-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/4176ba6f6afb/molecules-28-03396-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/e3eae45e5c99/molecules-28-03396-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/48e4b7185f37/molecules-28-03396-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/80c94fa6b934/molecules-28-03396-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/6e69901ac5d6/molecules-28-03396-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/5a3b26f8828c/molecules-28-03396-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/203fb544e093/molecules-28-03396-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6047/10141678/6df27a1ee5eb/molecules-28-03396-g009.jpg

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