Urbina-Suarez Néstor A, Rivera-Caicedo Christian, González-Delgado Ángel Darío, Barajas-Solano Andrés F, Machuca-Martínez Fiderman
Department of Environmental Sciences, Universidad Francisco de Paula Santander, Av. Gran Colombia No. 12E-96, Cucuta 540003, Colombia.
School of Natural Resources and Environment, Universidad del Valle, Ciudad Universitaria Meléndez, Calle 13 # 100-00, Cali 760015, Colombia.
Toxics. 2023 Apr 11;11(4):366. doi: 10.3390/toxics11040366.
The textile industry is a global economic driving force; however, it is also one of the most polluting industries, with highly toxic effluents which are complex to treat due to the recalcitrant nature of some compounds present in these effluents. This research focuses on the removal of Chemical Oxygen Demand (COD), color, Total Organic Carbon (TOC), and Ammoniacal Nitrogen (N-NH) on tannery wastewater treatment through an advanced oxidation process (AOPs) using sodium bicarbonate (NaHCO), hydrogen peroxide (HO) and temperature using a central composite non-factorial design with a surface response using Statistica 7.0 software. All experiments used a 500 mL reactor with 300 mL of tannery wastewater from a company in Cúcuta, Colombia. The physicochemical characterization was done to determine the significant absorbance peaks about the color in the wavelengths between 297 and 669 nm. Statistical analysis found that the concentration of NaHCO affects the removal of color and N-NH; however, it did not affect COD and TOC. The optimal process conditions for removing the different compounds under study were: NaHCO 1 M, HO 2 M, and 60 °C, with efficiencies of 92.35%, 31.93%, 68.85%, and 35.5% N-NH, COD, color, and TOC respectively. It can be concluded that AOPs using HO and NaHCO are recommended to remove color and N-NH.
纺织业是全球经济的驱动力之一;然而,它也是污染最严重的行业之一,其排放的高毒性废水由于含有某些难降解化合物而难以处理。本研究聚焦于通过使用碳酸氢钠(NaHCO₃)、过氧化氢(H₂O₂)的高级氧化工艺(AOPs)以及温度,采用中心复合非析因设计和Statistica 7.0软件进行表面响应,来去除制革废水的化学需氧量(COD)、色度、总有机碳(TOC)和氨氮(N-NH₃)。所有实验均使用一个500 mL的反应器,其中装有来自哥伦比亚库库塔一家公司的300 mL制革废水。进行了物理化学表征,以确定在297至669 nm波长范围内关于色度的显著吸收峰。统计分析发现,NaHCO₃的浓度会影响色度和N-NH₃的去除;然而,它对COD和TOC没有影响。去除所研究的不同化合物的最佳工艺条件为:NaHCO₃ 1 M、H₂O₂ 2 M和60 °C,N-NH₃、COD、色度和TOC的去除效率分别为92.35%、31.93%、68.85%和35.5%。可以得出结论,建议使用H₂O₂和NaHCO₃的AOPs来去除色度和N-NH₃。