Polymer Institute of the Slovak Academy of Sciences, Dúbravská cesta 9, 845 41 Bratislava, Slovakia; National Institute of Rheumatic Diseases, Nábrežie I. Krasku 4782/4, 921 12 Piešťany, Slovakia.
Department of Chemistry, Shahid Bahonar University of Kerman, Kerman 76169, Iran.
Int J Biol Macromol. 2023 Jul 1;242(Pt 1):124742. doi: 10.1016/j.ijbiomac.2023.124742. Epub 2023 May 5.
This study presents the development and characterization of a nanocomposite material, consisting of thermoplastic starch (TPS) reinforced with bentonite clay (BC) and encapsulated with vitamin B (VB). The research is motivated by the potential of TPS as a renewable and biodegradable substitute for petroleum-based materials in the biopolymer industry. The effects of VB on the physicochemical properties of TPS/BC films, including mechanical and thermal properties, water uptake, and weight loss in water, were investigated. In addition, the surface morphology and chemical composition of the TPS samples were analyzed using high-resolution SEM microscopy and EDS, providing insight into the structure-property relationship of the nanocomposites. The results showed that the addition of VB significantly increased the tensile strength and Young's modulus of TPS/BC films, with the highest values observed for nanocomposites containing 5 php of VB and 3 php of BC. Furthermore, the release of VB was controlled by the BC content, with higher BC content leading to lower VB release. These findings demonstrate the potential of TPS/BC/VB nanocomposites as environmentally friendly materials with improved mechanical properties and controlled release of VB, which can have significant applications in the biopolymer industry.
本研究提出了一种纳米复合材料的开发和特性研究,该复合材料由热塑性淀粉(TPS)增强膨润土(BC)组成,并封装有维生素 B(VB)。研究的动机是 TPS 作为一种可再生和可生物降解的替代石油基材料在生物聚合物行业中的潜在应用。研究考察了 VB 对 TPS/BC 薄膜的物理化学性能的影响,包括力学性能、热性能、吸水率和水中失重。此外,还使用高分辨率 SEM 显微镜和 EDS 分析了 TPS 样品的表面形貌和化学组成,深入了解了纳米复合材料的结构-性能关系。结果表明,VB 的添加显著提高了 TPS/BC 薄膜的拉伸强度和杨氏模量,含有 5 phr VB 和 3 phr BC 的纳米复合材料表现出最高的值。此外,VB 的释放受 BC 含量的控制,BC 含量越高,VB 的释放越低。这些发现表明 TPS/BC/VB 纳米复合材料作为具有改善力学性能和 VB 控制释放的环境友好材料具有潜力,在生物聚合物行业中有重要的应用前景。