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叠氮化物-烯醇化物环加成-重排反应能够实现酰胺的直接α-氨化和酯到烯内酰胺的合成。

Azide-Enolate Cycloaddition-Rearrangement Enables Direct α-Amination of Amides and Enelactam Synthesis from Esters.

机构信息

School of Chemical Sciences and, Maurice Wilkins Centre for Molecular Biodiscovery, The University of Auckland, 23 Symonds St, Auckland, 1010, New Zealand.

School of Chemical & Physical Sciences, Victoria University of Wellington, Kelburn Parade, Wellington, 6012, New Zealand.

出版信息

Chemistry. 2023 Jun 2;29(31):e202301235. doi: 10.1002/chem.202301235. Epub 2023 May 11.

Abstract

Invited for the cover of this issue are Dan Furkert, Joe Bell-Tyrer and co-workers at the University of Auckland and Victoria University of Wellington. The image depicts a tandem cycloaddition-rearrangement process delivering a diverse range of molecular frameworks from simple precursors. Read the full text of the article at 10.1002/chem.202300261.

摘要

本期杂志的封面邀请到了奥克兰大学和惠灵顿维多利亚大学的 Dan Furkert、Joe Bell-Tyrer 及其同事。该图片描绘了一个串联环加成-重排过程,从简单的前体中构建了多样化的分子骨架。全文请阅读 10.1002/chem.202300261。

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