Zhou Xuan, Mao Zhongyang, Luo Penghui, Deng Min
College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211800, China.
State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing 211800, China.
Materials (Basel). 2023 Apr 28;16(9):3448. doi: 10.3390/ma16093448.
Shrinkage deformation of concrete has been one of the difficulties in the process of concrete performance research. Cracking of concrete caused by self-shrinkage and temperature-drop shrinkage has become a common problem in the concrete world, and cracking leads to a decrease in the durability of concrete and even a safety hazard. Mineral admixtures, such as fly ash and mineral powder, are widely used to improve the temperature drop shrinkage of mass concrete; fly ash can reduce the temperature rise of concrete while also reducing the self-shrinkage of concrete, there are different results on the effect of mineral powder on the self-shrinkage of concrete, but the admixture of fly ash will reduce the strength of concrete, and mineral admixtures have an inhibitory effect on the shrinkage compensation effect of MgO expander(MEA). The paper investigates the effect of mineral admixtures on the mechanical and deformation properties of C50 mass concrete with a MgO expander(MEA), aiming to determine the proportion of C50 mass concrete with good anti-cracking properties under working conditions. The experiments investigated the effect of fly ash admixture, mineral powder admixture and MgO expander admixture on the compressive strength and deformation of concrete under simulated working conditions of variable temperature and analyzed the effect of hydration of magnesite in MgO expander and pore structure of cement paste on deformation. The following main conclusions were obtained: 1. When the concrete compounded with mineral admixture was cured under variable temperature conditions, the compounded 30% fly ash and mineral powder decreased by 4.3%, 6.0% and 8.4% at 7d age, and the compounded 40% fly ash and mineral powder decreased by 3.4%, 2.8% and 2.3% at 7d age, respectively. The incorporation of MEA reduced the early compressive strength of concrete; when the total amount of compounding remained unchanged, the early compressive strength of concrete was gradually smaller as the proportion of compounding decreased. 2. The results of concrete deformation showed that when the temperature rose, the concrete expanded rapidly, and when the temperature dropped, the concrete also showed a certain shrinkage, and the deformation of concrete basically reached stability at 18d. 3. The compounding of 30% fly ash and mineral powder As the compounding ratio decreases, the deformation of concrete increases, and the 28d deformation of concrete with a compounding ratio of 2:1 is 280 × 10, while the final stable deformation of concrete with a compounding ratio of 2:1 in compounding 40% fly ash and mineral powder is the largest, with a maximum value of 230 × 10, respectively. Overall, the concrete with a total compounding of 30% and a compounding ratio of 2:1 has the best shrinkage resistance performance.
混凝土的收缩变形一直是混凝土性能研究过程中的难题之一。由自收缩和温降收缩引起的混凝土开裂已成为混凝土领域的常见问题,而开裂会导致混凝土耐久性下降,甚至产生安全隐患。粉煤灰和矿粉等矿物掺合料被广泛用于改善大体积混凝土的温降收缩;粉煤灰可以降低混凝土的温升,同时也能减少混凝土的自收缩,关于矿粉对混凝土自收缩的影响存在不同结果,但粉煤灰的掺入会降低混凝土的强度,且矿物掺合料对MgO膨胀剂(MEA)的收缩补偿效果有抑制作用。本文研究了矿物掺合料对掺MgO膨胀剂(MEA)的C50大体积混凝土力学性能和变形性能的影响,旨在确定在工作条件下具有良好抗裂性能的C50大体积混凝土的配合比。试验研究了粉煤灰掺量、矿粉掺量和MgO膨胀剂掺量在变温模拟工作条件下对混凝土抗压强度和变形的影响,并分析了MgO膨胀剂中菱镁矿水化及水泥浆体孔结构对变形的影响。得到以下主要结论:1. 掺矿物掺合料的混凝土在变温条件下养护时,掺30%粉煤灰和矿粉的混凝土在7d龄期时抗压强度分别降低了4.3%、6.0%和8.4%,掺40%粉煤灰和矿粉的混凝土在7d龄期时抗压强度分别降低了3.4%、2.8%和2.3%。掺入MEA降低了混凝土的早期抗压强度;当总掺量不变时,随着掺量比例降低,混凝土的早期抗压强度逐渐变小。2. 混凝土变形结果表明,温度升高时混凝土迅速膨胀,温度降低时混凝土也表现出一定收缩,混凝土变形在18d基本达到稳定。3. 掺30%粉煤灰和矿粉时,随着掺合比降低,混凝土变形增大,掺合比为2:1的混凝土28d变形为280×10,而掺40%粉煤灰和矿粉且掺合比为2:1的混凝土最终稳定变形最大,最大值分别为230×10。总体而言,总掺量为30%且掺合比为2:1的混凝土抗收缩性能最佳。