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水胶比对掺MgO膨胀剂的C50大体积混凝土自收缩的影响

Effect of the Water-Binder Ratio on the Autogenous Shrinkage of C50 Mass Concrete Mixed with MgO Expansion Agent.

作者信息

Chen Jun, Mao Zhongyang, Huang Xiaojun, Deng Min

机构信息

College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211816, China.

State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211800, China.

出版信息

Materials (Basel). 2023 Mar 21;16(6):2478. doi: 10.3390/ma16062478.

Abstract

The high adiabatic temperature rise and low heat dissipation rate of mass concrete will promote rapid hydration of the cementitious material and rapid consumption of water from the concrete pores, which may significantly accelerate the development of concrete autogenous shrinkage. In this study, the effect of the water-binder ratio on the autogenous shrinkage of C50 concrete mixed with MgO expansion agent (MEA) was explained with respect to mechanical properties, pore structure, degree of hydration, and micromorphology of the concrete based on a variable temperature curing chamber. The results show that the high temperature rise within the mass concrete accelerates the development of early (14 d) autogenous shrinkage of the concrete, and that the smaller the water-binder ratio, the greater the autogenous shrinkage of the concrete. With the addition of 8 wt% MEA, the autogenous shrinkage of concrete can be effectively compensated. The larger the water-binder ratio, the higher the degree of MgO hydration, and in terms of the compensation effect of autogenous shrinkage, the best performance is achieved at a water-binder ratio of 0.36. This study provides a data reference for the determination of the water-binder ratio in similar projects with MEA.

摘要

大体积混凝土的高绝热温升和低热散失率会促进胶凝材料的快速水化以及混凝土孔隙中水的快速消耗,这可能会显著加速混凝土自收缩的发展。在本研究中,基于变温养护箱,从混凝土的力学性能、孔结构、水化程度和微观形貌等方面,阐述了水胶比对掺氧化镁膨胀剂(MEA)的C50混凝土自收缩的影响。结果表明,大体积混凝土内部的高温升加速了混凝土早期(14 d)自收缩的发展,且水胶比越小,混凝土的自收缩越大。掺入8 wt%的MEA可有效补偿混凝土的自收缩。水胶比越大,氧化镁的水化程度越高,就自收缩补偿效果而言,水胶比为0.36时性能最佳。本研究为含MEA的类似工程中水胶比的确定提供了数据参考。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b974/10051540/eca28e69504e/materials-16-02478-g001.jpg

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