Faculty of Sciences of Gabes, RL Processes, Energetic, Environment and Electric Systems (PEESE), University of Gabes, 6072, Gabes, Tunisia.
Department of Chemical Engineering, Universitat Rovira I Virgili, 43007, Tarragona, Spain.
Environ Sci Pollut Res Int. 2023 Jun;30(30):74544-74574. doi: 10.1007/s11356-023-27484-2. Epub 2023 May 25.
An exponential rise in global pollution and industrialization has led to significant economic and environmental problems due to the insufficient application of green technology for the chemical industry and energy production. Nowadays, the scientific and environmental/industrial communities push to apply new sustainable ways and/or materials for energy/environmental applications through the so-called circular (bio)economy. One of today's hottest topics is primarily valorizing available lignocellulosic biomass wastes into valuable materials for energy or environmentally related applications. This review aims to discuss, from both the chemistry and mechanistic points of view, the recent finding reported on the valorization of biomass wastes into valuable carbon materials. The sorption mechanisms using carbon materials prepared from biomass wastes by emphasizing the relationship between the synthesis route or/and surface modification and the retention performance were discussed towards the removal of organic and heavy metal pollutants from water or air (NO, CO, VOCs, SO, and Hg). Photocatalytic nanoparticle-coated biomass-based carbon materials have proved to be successful composites for water remediation. The review discusses and simplifies the most raised interfacial, photonic, and physical mechanisms that might take place on the surface of these composites under light irradiation. Finally, the review examines the economic benefits and circular bioeconomy and the challenges of transferring this technology to more comprehensive applications.
全球污染和工业化的指数级增长,由于绿色技术在化学工业和能源生产中的应用不足,导致了重大的经济和环境问题。如今,科学界和环境/工业界都在推动通过所谓的循环(生物)经济,为能源/环境应用采用新的可持续方法和/或材料。当今最热门的话题之一是,主要将现有的木质纤维素生物质废物转化为有价值的材料,用于能源或与环境相关的应用。本综述旨在从化学和机械的角度讨论最近报道的将生物质废物转化为有价值的碳材料的研究成果。通过强调合成路线或/和表面改性与保留性能之间的关系,讨论了利用生物质废物制备的碳材料的吸附机制,以去除水中或空气中的有机和重金属污染物(NO、CO、VOCs、SO 和 Hg)。负载纳米颗粒的基于生物质的碳材料已被证明是水修复的成功复合材料。本综述讨论并简化了在光照射下这些复合材料表面可能发生的最主要的界面、光子和物理机制。最后,综述考察了该技术向更全面应用转移的经济利益、循环生物经济和挑战。