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羧甲基纤维素-g-聚(丙烯酸-co-丙烯酰胺)/聚乙烯醇海绵的合成作为一种快速吸收剂复合材料及其在珊瑚砂土壤中的应用。

Synthesis of carboxymethyl cellulose-g-poly (acrylic acid-co-acrylamide)/polyvinyl alcohol sponge as a fast absorbent composite and its application in coral sand soil.

机构信息

Key Laboratory of Three Gorges Reservoir Region's Eco-Environment, Ministry of Education, Chongqing University, Chongqing 400045, PR China.

Key Laboratory of Three Gorges Reservoir Region's Eco-Environment, Ministry of Education, Chongqing University, Chongqing 400045, PR China.

出版信息

Int J Biol Macromol. 2023 Jul 1;242(Pt 3):124965. doi: 10.1016/j.ijbiomac.2023.124965. Epub 2023 May 24.

Abstract

To improve the rapid absorption capacity of coral sand soil for rainfall, a composite of carboxymethyl cellulose-g-poly (acrylic acid-co-acrylamide)/polyvinyl alcohol sponge (CMC-g-P(AA-co-AM)/PVA) was designed and synthesized by coupling CMC-g-P(AA-co-AM) granules with a PVA sponge. The results showed that the rapid water absorption of CMC-g-P (AA-co-AM)/PVA in distilled water in 1 h was 26.45 g/g, twice that of CMC-g-P(AA-co-AM) and the PVA sponge, which is suitable for short-term rainfall. In addition, the cation had a slight influence on the water absorption capacity of CMC-g-P (AA-co-AM)/PVA, which were 29.5 and 18.9 g/g in 0.9 wt% NaCl and CaCl solutions, respectively, indicating the great adaptability of CMC-g-P (AA-co-AM)/PVA to high‑calcium coral sand. With the addition of 2 wt% CMC-g-P (AA-co-AM)/PVA, the water interception ratio of the coral sand increased from 13.8 % to 23.7 %, and 54.6 % of the total interception water remained after 15-day evaporation. Moreover, pot experiments demonstrated that 2 wt% CMC-g-P(AA-co-AM)/PVA in coral sand enhanced plant development under water scarcity, suggesting that CMC-g-P (AA-co-AM)/PVA is a promising soil amendment for coral sand soils.

摘要

为提高珊瑚砂土壤对降雨的快速吸收能力,通过将羧甲基纤维素-g-聚(丙烯酸-co-丙烯酰胺)/聚乙烯醇海绵(CMC-g-P(AA-co-AM)/PVA)颗粒与 PVA 海绵偶联,设计并合成了 CMC-g-P(AA-co-AM)/PVA 复合材料。结果表明,CMC-g-P(AA-co-AM)/PVA 在蒸馏水中 1 h 的快速吸水率为 26.45 g/g,是 CMC-g-P(AA-co-AM)和 PVA 海绵的 2 倍,适用于短期降雨。此外,阳离子对 CMC-g-P(AA-co-AM)/PVA 的吸水率有轻微影响,在 0.9 wt%NaCl 和 CaCl 溶液中的吸水率分别为 29.5 和 18.9 g/g,表明 CMC-g-P(AA-co-AM)/PVA 对高钙珊瑚砂具有很强的适应性。添加 2 wt%CMC-g-P(AA-co-AM)/PVA 后,珊瑚砂的截留率从 13.8%增加到 23.7%,15 天蒸发后截留的总水量仍有 54.6%。此外,盆栽实验表明,珊瑚砂中 2 wt%CMC-g-P(AA-co-AM)/PVA 增强了植物在缺水条件下的生长,表明 CMC-g-P(AA-co-AM)/PVA 是一种很有前途的珊瑚砂土壤改良剂。

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