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双组分硅烷基封端预聚物/环氧树脂胶粘剂潜在催化剂的研究

Research of Potential Catalysts for Two-Component Silyl-Terminated Prepolymer/Epoxy Resin Adhesives.

作者信息

Berzins Ritvars, Merijs-Meri Remo, Zicans Janis

机构信息

Institute of Polymer Materials, Faculty of Materials Science and Applied Chemistry, Riga Technical University, 3 Paula Valdena Street, LV-1048 Riga, Latvia.

出版信息

Polymers (Basel). 2023 May 11;15(10):2269. doi: 10.3390/polym15102269.

DOI:10.3390/polym15102269
PMID:37242844
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10221171/
Abstract

The current research is devoted to the research of potential catalysts for the two-component silyl-terminated prepolymer/epoxy resin system. The catalyst system must catalyze the prepolymer of the opposite component while not curing the prepolymer in the component in which the catalyst is located. Mechanical and rheological characterization of the adhesive was performed. The results of the investigation showed that certain alternative catalyst systems, which are less toxic, may be used instead of traditional catalysts for individual systems. Two-component systems, obtained by using these catalysts systems, cure in an acceptable time scale and demonstrate relatively high tensile strength and deformation values.

摘要

当前的研究致力于双组分硅烷基封端预聚物/环氧树脂体系潜在催化剂的研究。该催化剂体系必须催化相反组分的预聚物,同时又不会使催化剂所在组分中的预聚物固化。对粘合剂进行了力学和流变学表征。研究结果表明,某些毒性较小的替代催化剂体系可用于替代个别体系中的传统催化剂。使用这些催化剂体系获得的双组分体系在可接受的时间范围内固化,并表现出相对较高的拉伸强度和变形值。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/474f/10221171/2e41b22ad81b/polymers-15-02269-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/474f/10221171/ffa8a7042677/polymers-15-02269-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/474f/10221171/195d786c3ca6/polymers-15-02269-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/474f/10221171/ed5197d6ca11/polymers-15-02269-g003a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/474f/10221171/ee2829ece226/polymers-15-02269-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/474f/10221171/680181ed370a/polymers-15-02269-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/474f/10221171/676db594a812/polymers-15-02269-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/474f/10221171/e6f694853773/polymers-15-02269-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/474f/10221171/f3fb0cc6c655/polymers-15-02269-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/474f/10221171/2e41b22ad81b/polymers-15-02269-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/474f/10221171/ffa8a7042677/polymers-15-02269-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/474f/10221171/195d786c3ca6/polymers-15-02269-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/474f/10221171/ed5197d6ca11/polymers-15-02269-g003a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/474f/10221171/ee2829ece226/polymers-15-02269-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/474f/10221171/680181ed370a/polymers-15-02269-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/474f/10221171/676db594a812/polymers-15-02269-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/474f/10221171/e6f694853773/polymers-15-02269-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/474f/10221171/f3fb0cc6c655/polymers-15-02269-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/474f/10221171/2e41b22ad81b/polymers-15-02269-g009.jpg

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本文引用的文献

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Kinetics of Alkoxysilanes and Organoalkoxysilanes Polymerization: A Review.
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Polymers (Basel). 2019 Mar 21;11(3):537. doi: 10.3390/polym11030537.