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使用负载 Pd-Cu 纳米粒子的 Noria-GO 纳米复合材料高效还原硝基酚。

Efficient nitrophenol reduction with Noria-GO nanocomposite decorated with Pd-Cu nanoparticles.

机构信息

Department of Chemistry, College of Science, Jouf University, Sakaka, 2014, Saudi Arabia.

Department of Chemistry, College of Science, Jouf University, Sakaka, 2014, Saudi Arabia.

出版信息

Environ Res. 2023 Aug 15;231(Pt 3):116259. doi: 10.1016/j.envres.2023.116259. Epub 2023 May 27.

Abstract

We report a facile approach to synthesize Pd-Cu nanoparticles immobilized on a Noria-GO nanocomposite for efficient nitrophenol reduction. The unique architecture of the Noria and the hydrophilic nature of GO contribute to the improved performance and structure of the resulting nanocomposite. The simple sol-immobilization approach employed NaBH as a reductant and polyvinyl alcohol as a capping agent to evenly decorate small Pd-Cu nanoparticles with a diameter of 1.4 nm on the Noria-GO surface. The prepared Pd-Cu@Noria-GO nanocomposite was utilized as a nanocatalyst in converting of nitrophenol to aminophenol using NaBH solution. Our Pd-Cu@Noria-GO nanocomposite exhibited superior catalytic efficacy with large conversion percentages, K, and K values of 95%, 0.225 min, and 225 ming, respectively. X-ray photoemission spectroscopy confirmed the oxidation state of the prepared nanoparticles, and TEM findings demonstrated the homogenous decoration of Pd-Cu NPs on the Noria-GO surface. Additionally, the durability of the Pd-Cu@Noria-GO nanocomposite shown its potential as a robust and promising material for remediating organic contaminants. Our results indicate that Pd-Cu@Noria-GO nanocomposite can be an effective and sustainable approach for mitigating the hazards associated with nitrophenols.

摘要

我们报告了一种简便的方法,用于合成负载在 Noria-GO 纳米复合材料上的 Pd-Cu 纳米粒子,以实现高效的硝基苯酚还原。Noria 的独特结构和 GO 的亲水性有助于提高所得纳米复合材料的性能和结构。所采用的简单溶胶固载方法以 NaBH 为还原剂,以聚乙烯醇为封端剂,将直径为 1.4nm 的小 Pd-Cu 纳米粒子均匀地装饰在 Noria-GO 表面上。制备的 Pd-Cu@Noria-GO 纳米复合材料被用作纳米催化剂,在 NaBH 溶液中将硝基苯酚转化为氨基酚。我们的 Pd-Cu@Noria-GO 纳米复合材料表现出优异的催化效果,转化率、K 和 K 值分别为 95%、0.225min 和 225ming。X 射线光电子能谱证实了制备的纳米粒子的氧化态,TEM 结果表明 Pd-Cu NPs 均匀地装饰在 Noria-GO 表面上。此外,Pd-Cu@Noria-GO 纳米复合材料的耐用性表明其作为一种用于修复有机污染物的坚固、有前途的材料具有潜力。我们的结果表明,Pd-Cu@Noria-GO 纳米复合材料可以成为一种有效和可持续的方法,用于减轻与硝基苯酚相关的危害。

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