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一种基于高性能金属卤化物钙钛矿的激光驱动显示器。

A high-performance metal halide perovskite-based laser-driven display.

作者信息

Zhang Shaoan, Li Zhenzhang, Fang Zaijin, Qiu Bao, Pathak Janak L, Sharafudeen Kaniyarakkal, Saravanakumar S, Li Zhanjun, Han Gang, Li Yang

机构信息

Faculty of Electrical Engineering and Computer Science, Ningbo University, Ningbo, 315211, China.

School of Biomedical Engineerings, Guangzhou Medical University, Guangzhou, Guangdong, 511436, China.

出版信息

Mater Horiz. 2023 Aug 29;10(9):3499-3506. doi: 10.1039/d3mh00507k.

Abstract

Laser-driven liquid crystal displays (LCDs) comprising metal halide perovskites (MHPs) as the blue-to-green/red color converters are at the forefront of ongoing intense research on the development and improvement of display devices. However, the inferior high photoluminescence quantum yield (PLQY) of MHPs under the excitation of high-power blue light and photoluminescence deterioration at high temperatures remain major concerns. Herein, we design a kind of octylamine-modified MHP binding energy engineering, and the synthesized materials show PLQY of 97.6% under the excitation of a blue laser at 450 nm. Meanwhile, this design endows a structural self-healing ability to achieve a high PLQY and luminescence stability under high temperature (90 °C) and high flux excitation (386 mW cm). The blue light-excitable MHPs with a near unity PLQY, strong stability, and low PLQY deterioration are further encapsulated into a laser-driven LCD device. This prototype demonstrates excellent color gamut (132% NTSC, 98% Rec. 2020), illuminance intensity (>10 000 lux), and energy consumption (47.5% of commercial consumption), and hence is expected to be beneficial for the reduction of energy consumption in backlight display devices, particularly in large-screen outdoor displays.

摘要

以金属卤化物钙钛矿(MHP)作为蓝到绿/红颜色转换器的激光驱动液晶显示器(LCD),处于当前显示器设备开发与改进的深入研究前沿。然而,MHP在高功率蓝光激发下较低的高光致发光量子产率(PLQY)以及在高温下的光致发光劣化仍是主要问题。在此,我们通过辛胺修饰的MHP结合能工程进行设计,合成的材料在450 nm蓝光激光激发下显示出97.6%的PLQY。同时,这种设计赋予了结构自修复能力,以在高温(90°C)和高通量激发(386 mW cm)下实现高PLQY和发光稳定性。具有接近单位PLQY、强稳定性和低PLQY劣化的蓝光可激发MHP进一步封装到激光驱动的LCD器件中。该原型展示了优异的色域(132% NTSC,98% Rec. 2020)、照度强度(>10000勒克斯)和能耗(商业能耗的47.5%),因此有望有利于降低背光显示设备的能耗,特别是在大屏幕户外显示器中。

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