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源自生物合成和物理改性的可食用、高强度且低吸湿性的细菌纤维素用于食品包装。

Edible, strong, and low-hygroscopic bacterial cellulose derived from biosynthesis and physical modification for food packaging.

作者信息

Cheung Ka Man, Jiang Zhuolun, Ngai To

机构信息

Department of Chemistry, The Chinese University of Hong Kong, Hong Kong, Shatin, China.

出版信息

J Sci Food Agric. 2023 Oct;103(13):6625-6639. doi: 10.1002/jsfa.12758. Epub 2023 Jun 15.

Abstract

BACKGROUND

The pervasive presence of plastic packaging has led to significant environmental contamination due to excessive reliance on petrochemicals and the inherent non-biodegradability of these materials. Bacterial cellulose (BC) films present a viable alternative for food packaging applications, owing to their environmentally friendly synthesis process, non-toxic nature, robust mechanical strength, and biodegradability. However, the high hygroscopicity of such bio-based materials has limited their widespread adoption, as it results in diminished strength and barrier properties. In this study, a novel approach for creating edible, transparent, robust, and high-barrier BC-based composite packaging was proposed through biosynthesis with the incorporation of soy protein isolate and the physical interpenetration of calcium alginate-polyethylene glycol as a composite coating.

RESULTS

The finding demonstrated that the synthesized bio-based composite material exhibits stability in water, high optical transparency, complete oil resistance, and full degradability within 1 to 2 months. Furthermore, the composite material displayed enhanced mechanical properties in both dry and wet conditions, with a tensile strength of approximately 84 MPa, outperforming commercially available kraft paper and low-density polyethylene.

CONCLUSIONS

Soy protein isolate established a rigid, coherent, and homogeneous network with BC fibrils, thereby augmenting mechanical properties. Calcium alginate can be effectively combined with BC, utilizing polyethylene glycol as a binder and plasticizer, to generate a densely packed structure with reduced hygroscopicity. This bio-based composite material demonstrated considerable potential for application in food packaging and other value-added sectors as a substitute for non-degradable plastics. © 2023 Society of Chemical Industry.

摘要

背景

由于过度依赖石化产品以及这些材料固有的不可生物降解性,塑料包装的普遍存在已导致严重的环境污染。细菌纤维素(BC)薄膜因其环境友好的合成过程、无毒性质、强大的机械强度和生物降解性,为食品包装应用提供了一种可行的替代方案。然而,这种生物基材料的高吸湿性限制了它们的广泛应用,因为这会导致强度和阻隔性能下降。在本研究中,通过生物合成并结合大豆分离蛋白以及将海藻酸钙 - 聚乙二醇作为复合涂层进行物理互穿,提出了一种制备可食用、透明、坚固且具有高阻隔性的基于BC的复合包装的新方法。

结果

研究结果表明,合成的生物基复合材料在水中具有稳定性、高光学透明度、完全耐油性,并且在1至2个月内可完全降解。此外,该复合材料在干燥和潮湿条件下均表现出增强的机械性能,拉伸强度约为84 MPa,优于市售牛皮纸和低密度聚乙烯。

结论

大豆分离蛋白与BC原纤维形成了刚性、连贯且均匀的网络,从而增强了机械性能。海藻酸钙可以与BC有效结合,利用聚乙二醇作为粘合剂和增塑剂,形成紧密堆积的结构,降低吸湿性。这种生物基复合材料作为不可降解塑料的替代品,在食品包装和其他增值领域显示出巨大的应用潜力。© 2023化学工业协会。

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