University of Wrocław, Faculty of Chemistry, 14 F. Joliot-Curie St., 50-383 Wrocław, Poland.
Chem Commun (Camb). 2023 Jun 15;59(49):7579-7582. doi: 10.1039/d3cc01706k.
The CuAAC active-template approach was exploited to construct rotaxanes incorporating cage-like silsesquioxane stoppers, namely, POSSaxanes. The compounds were characterized in the solution and solid state, providing the unprecedented molecular structures of POSS-incorporating rotaxanes.
该研究采用铜催化的叠氮-炔环加成（CuAAC）活性模板法，构建了笼型硅倍半氧烷（POSS）止轮烷，即 POSSaxanes。在溶液和固态下对化合物进行了表征，提供了含 POSS 的轮烷前所未有的分子结构。
