Overstreet Shayla M J, Genzia Ian M, Nguyen Alexander, Auleciems Zachary J, Jennings Abby R, Peloquin Andrew J
Department of Chemistry, United States Air Force Academy, Colorado Springs, CO 80840, USA.
Acta Crystallogr E Crystallogr Commun. 2023 May 26;79(Pt 6):571-574. doi: 10.1107/S2056989023004334. eCollection 2023 May 1.
In the title compound, CHFNO, the conformation about the N-C-C-O bond is [torsion angle = 61.84 (13)°]. In the crystal, N-H⋯O hydrogen bonds link the mol-ecules into [010] chains, which are cross-linked by C-H⋯F and C-H⋯π contacts. Hirshfeld surface analysis was conducted to aid in the visualization of these various influences on the packing. This analysis showed that the largest contribution to the surface contacts arises from F⋯H/H⋯F inter-actions (35.6%), followed by O⋯H/H⋯O (17.8%) and H⋯H (12.7%).